| 释义 |
diene Chem.|ˈdaɪiːn|
[f. di-2 + -ene.]
a. Any organic compound containing two double bonds between carbon atoms.
1917Chem. Abstr. XI. 3031 (title) The melting points of hydrocarbons, especially dienes, having a system of conjugated double bonds. 1929Ibid. XXIII. 3232 Dienes such as isoprene in relatively pure condition. 1961L. F. & M. Fieser Adv. Org. Chem. v. 197 Butadiene is significantly more stable..than dienes with isolated (nonconjugated) double bonds.
b. attrib., esp. in diene synthesis, an addition reaction in which two carbon atoms joined by a double or triple bond in an unsaturated compound become attached to the first and fourth carbon atoms of a conjugated diene, forming a ring of six carbon atoms in the resulting molecule; the Diels-Alder reaction; diene value, a number expressing the degree of unsaturation in fatty compounds.
1928Chem. Abstr. XXII. 1144 (heading) Addition of ‘diene’ hydrocarbons.
1930Ibid. XXIV. 356 (heading) The ‘diene-syntheses’. An ideal method for the synthesis of organic compounds. 1957Encycl. Brit. I. 549/2 The diene synthesis consists essentially of the addition of substances containing two conjugate double bonds, such as the butadienes, to substances such as maleic acid or quinones.
1936Rep. Prog. Applied Chem. 433 Linseed oil itself shows a definite ‘maleic’ or ‘diene value’, equivalent to about 5–7% of conjugated triene glycerides. |