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单词 vibronic
释义 vibronic, a. Physics.|vaɪˈbrɒnɪk|
[f. vibrational a. + electronic a.]
Of or pertaining to electronic energy levels or transitions associated with the vibration of the constituent atoms of a molecule.
1941R. S. Mulliken in Physical Rev. LIX. 880/2 The vibronic wave function ψev is a function of the electronic and vibrational coordinates.1966G. Herzberg Molecular Spectra & Molecular Structure i. 22 For half-integral spin we have two-valued vibronic species.1976Nature 22 Apr. 675/1 No vibronic structure has been detected in the absorption spectrum of the chromophore of the rhodopsin.
Hence viˈbronically adv.
1966D. H. Whiffen Spectroscopy xii. 160 Transitions which are permitted solely on this account are called vibronic transitions or may be said to be vibronically allowed.1978Nature 19 Jan. 236/2 The results indicate that the afterglow is due to an emission to S0 of the monomer or to a vibronically similar ground state.
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