| 释义 |
mercurate, v. Chem.|ˈmɜːkjʊəreɪt|
[f. Mercury n. + -ate3.]
trans. To convert into a mercury derivative, esp. by replacing a hydrogen atom in an aromatic ring by a group containing mercury
1923Org. Syntheses III. 14 Phenol has been mercurated in water solution. 1942Fuson & Snyder Org. Chem. xxxi. 430 Hydrocarbons are mercurated by treatment at 90–160° for one or more hours. 1967I. L. Finar Org. Chem. (ed. 5) I. xx. 583 Aromatic compounds containing almost all the common functional groups have been mercurated.
So ˈmercurated ppl. a.; mercuˈration, the process of mercurating or of becoming mercurated.
1921Jrnl. Amer. Chem. Soc. XLIII. 621 The 3 mercurated phenols were boiled with aqueous potassium iodide. 1923Org. Syntheses III. 100 p-Tolylmercuric chloride has been prepared..by the direct mercuration of toluene with mercuric acetate. 1965Phillips & Williams Inorg. Chem. I. xi. 420 Mercuration of aromatic systems occurs very rapidly, presumably through a similar intermediate. 1967I. L. Finar Org. Chem. (ed. 5) I. xx. 584 The position of the acetoxymercuri-group can be found by treating the mercurated compound with halogen. |