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单词 co-ordination number
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co-ordination number
5. Chemistry. The formation or existence of a co-ordinate bond; linking by means of a co-ordinate bond; frequently attributive, esp. in co-ordination number [translating German koordinationszahl (A. Werner 1893, in Zeitschrift für anorg. Chemie III. 326)] , (a) in a co-ordination compound, the number of atoms or groups linked to the central atom or group by co-ordinate or covalent bonds; (b) in a crystal, the number of ions immediately surrounding any given molecule or ion.
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co-ordination1902
1902 Jrnl. Chem. Soc. 82 ii. 555 The capacity for combination of an atom is determined by three factors, principal valency, supplementary valency, and the co-ordination constant.
1908 Jrnl. Chem. Soc. 93 ii. 1571 Whatever co-ordination number the central atom may have.
1938 C. W. Stillwell Crystal Chem. i. 13 For AX2 compounds there will be two coordination numbers, for there are twice as many ions (or atoms) X as there are ions (or atoms) A.
1939 Thorpe's Dict. Appl. Chem. (ed. 4) III. 330/1 The prevalence of co-ordination numbers 4 and 6 suggested that co-ordination compounds had a spatial arrangement..corresponding respectively with the tetrahedron and octahedron.
1950 Chem. Rev. 46 389 These cyclic tertiary bases have a spatial configuration which is far more favorable to coördination with a metal ion.
1953 C. K. Ingold Struct. & Mech. Org. Chem. v. 205 The covalent bond can be formed by co-ordination.
1955 G. L. Clark Appl. X-rays (ed. 4) xvii. 522 Coordination of NH3 molecules around the cation as in Co(NH3)6Cl3.
1962 P. J. Durrant & B. Durrant Introd. Adv. Inorg. Chem. xii. 345 In the hexagonal and face-centred cubical close-packed structures the co~ordination number is 12.
1966 McGraw-Hill Encycl. Sci. & Technol. (rev. ed.) III. 457/2 The products formed are coordination ions or compounds, and this area of chemistry is known as coordination chemistry.
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