单词 | cryptate |
释义 | cryptaten. Chemistry. A coordination complex in which a metal cation is bound within a cavity in the molecule of a cryptand. ΘΚΠ the world > matter > chemistry > organic chemistry > organometallurgy > [noun] > complex cryptate1969 1969 Tetrahedron Lett.: Subject/Author Index Nos.1–60 p. ix/2 Cryptates, metal cation inclusion complexes, into molecular cavity of bicyclic ligands, 2889. 1984 N. N. Greenwood & A. Earnshaw Chem. of Elements (1986) v. 137 Cryptates..are also known and usually follow the stability sequence Mg < Ca < Sr < Ba. 2003 tr. F. Leroy Cent. of Nobel Prizes Recipients 92 Such an organic compound has..a three-dimensional cagelike molecular structure. The inner space is sufficient to accommodate various ions and form a cryptate. This entry has been updated (OED Third Edition, June 2011; most recently modified version published online March 2022). < n.1969 |
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