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单词 acyl
释义

acyln.

Brit. /ˈeɪsʌɪl/, /ˈasɪl/, U.S. /ˈæs(ə)l/
Origin: A borrowing from Latin, combined with an English element. Etymons: Latin acētum , -yl suffix.
Etymology: < ac- (in classical Latin acētum acetum n.) + -yl suffix. In sense 1 probably after German Acyl (1840 or earlier).
Chemistry.
1. = acetyl n. 1. Obsolete. rare.
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the world > matter > chemistry > organic chemistry > organic radicals > [noun] > miscellaneous named
hydrochloruret1834
spiroil1838
acetyl1840
valeryl1852
menthyl1862
vinyl1863
acyl1864
ethoxyl1866
carbylamine1868
thymyl1868
vanillyl1876
thienyl1885
thiocarbonyl1887
adenyl1889
iodonium1894
tetrazolium1895
sulphydryl1901
phytyl1911
pantoyl1942
ribosyl1945
pipsyl1946
hexanoyl1949
thiol1951
adenylyl1953
lipoyl1960
1864 A. W. Hoffmann in Chem. News 27 Feb. 105/1 The base itself, diphenyl-acyl-diamine, is a magnificently crystalline compound, and is built up as follows [formula shows](C2H3)′′′.
1864 Jrnl. Sci. Apr. 288 The names of these new bodies, diphenyl-formyl-diamine, and diphenyl-acyl-diamine, show them to be of interest only to advanced chemists.
2. A group or radical with the general formula —C(O)R (where R is an alkyl group), derived from a carboxylic acid. Chiefly attributive or as a formative element in names.
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the world > matter > chemistry > organic chemistry > organic radicals > [noun] > derived from an acid
citryl1858
acyl1910
1910 Encycl. Brit. III. 756/1 With formic or acetic acids..the para-semidines give acyl products possessing no basic character.
1959 Times 6 Mar. 13/7 Various penicillins can be regarded as acyl derivatives.
1977 J. March Adv. Org. Chem. (ed. 2) xviii. 963 The decomposition of acyl azides is one of several ways in which nitrenes are formed.
2010 Life Sci. Weekly (Nexis) 3 Aug. Acetyl substitution was very variable, producing a mixture of repeating units containing zero to four acyl groups.
This entry has been updated (OED Third Edition, December 2011; most recently modified version published online December 2021).
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