allylinn.

Brit.

/ˈalʌɪlɪn/,

/ˈalɪlɪn/, U.S.

/ˈælɪlɪn/

Forms: 1800s allyline, 1800s– allylin.

Origin: Formed within English, by derivation; perhaps modelled on a German lexical item, or perhaps modelled on a French lexical item. Etymons: allyl n., -in suffix¹.

Etymology: < allyl n. + -in suffix¹, perhaps after either German Allylin (1860 or earlier) or French allyline (1864 or earlier).

Chemistry. Now rare.

A viscous liquid formed by heating glycerol with oxalic acid.Allylin (also called monoallylin) is allyloxyglycerol; CH₂=CHCH₂OCH₂CH(OH)CH₂OH. Diallylin and triallylin may be formed if the second and third OH groups in the glycerol component are substituted with allyl radicals.

ΚΠ

1863 H. Watts Dict. Chem. I. 143 (heading) Oxide of allyl and glyceryl, or triallylin.]

1864 Chem. News 9 Apr. 176/1 Allyline combined in a similar manner with idriodic acid.

1873 Brit. Med. Jrnl. 18 Oct. 471/2 Croton-chloral..may be prepared by passing chlorine gas into allyline.

1875 H. Watts Dict. Chem., 2nd Supp. 51 Allylin is distinguished from glycerin-ether..both by its composition and by its reactions, glycerin-ether not being decomposed by distillation, and not combining with bromine.

1919 P. E. Spielman tr. V. von Richter Org. Chem. I. 531 Allylin..is produced by heating glycerol with oxalic acid.

This entry has been updated (OED Third Edition, September 2012; most recently modified version published online December 2021).

单词	allylin
释义	allylinn. Brit. /ˈalʌɪlɪn/, /ˈalɪlɪn/, U.S. /ˈælɪlɪn/ Forms: 1800s allyline, 1800s– allylin. Origin: Formed within English, by derivation; perhaps modelled on a German lexical item, or perhaps modelled on a French lexical item. Etymons: allyl n., -in suffix¹. Etymology: < allyl n. + -in suffix¹, perhaps after either German Allylin (1860 or earlier) or French allyline (1864 or earlier). Chemistry. Now rare. A viscous liquid formed by heating glycerol with oxalic acid.Allylin (also called monoallylin) is allyloxyglycerol; CH₂=CHCH₂OCH₂CH(OH)CH₂OH. Diallylin and triallylin may be formed if the second and third OH groups in the glycerol component are substituted with allyl radicals. ΚΠ 1863 H. Watts Dict. Chem. I. 143 (heading) Oxide of allyl and glyceryl, or triallylin.] 1864 Chem. News 9 Apr. 176/1 Allyline combined in a similar manner with idriodic acid. 1873 Brit. Med. Jrnl. 18 Oct. 471/2 Croton-chloral..may be prepared by passing chlorine gas into allyline. 1875 H. Watts Dict. Chem., 2nd Supp. 51 Allylin is distinguished from glycerin-ether..both by its composition and by its reactions, glycerin-ether not being decomposed by distillation, and not combining with bromine. 1919 P. E. Spielman tr. V. von Richter Org. Chem. I. 531 Allylin..is produced by heating glycerol with oxalic acid. This entry has been updated (OED Third Edition, September 2012; most recently modified version published online December 2021). < n.1864
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