exciplexn.

/ˈɛksɪplɛks/

Etymology: < exci- (in excited adj.) + -plex (in complex n.).

Chemistry.

A molecule formed by a metastable bond between two atoms or molecules and existing only in an excited state, from which it dissociates into the constituent atoms or molecules. Cf. excimer n.

ΘΚΠ

the world > matter > chemistry > atomic chemistry > [noun] > molecules > other molecules

supermolecule1834

open chain1880

excimer1960

exciplex1966

superatom1972

1966 M. Walker et al. in Jrnl. Chem. Physics 3456/1 The results appear to confirm the existence of 1:2 excited complex states, which we have termed exciplex states, for both solutes.

1972 C. H. DePuy & O. L. Chapman Molecular Reactions & Photochem. iv. 50 It is probable that the reaction involves an exciplex..that collapses to the biradical.

1976 K. Davis in R. Foster Molecular Association I. iii. 187 For systems in which no ground-state complex formation is detectable, formation of a complex is possible between an excited donor (or acceptor) and a ground-state acceptor (or donor)... Such a complex has been termed..an ‘exciplex’ or excited state complex and is similar to the complex formed between an excited-state molecule and a ground-state molecule of the same species termed an excimer.

1984 Science 23 Nov. 917/1 Electronically excited molecules, being better electron donors and acceptors than their ground states, form charge-transfer complexes (exciplexes) which can lead to radical ions. Exciplex emission is widely used to probe polymers and organized media such as membranes and micelles.

This entry has not yet been fully updated (first published 1989; most recently modified version published online June 2018).

单词	exciplex
释义	exciplexn. /ˈɛksɪplɛks/ Etymology: < exci- (in excited adj.) + -plex (in complex n.). Chemistry. A molecule formed by a metastable bond between two atoms or molecules and existing only in an excited state, from which it dissociates into the constituent atoms or molecules. Cf. excimer n. ΘΚΠ the world > matter > chemistry > atomic chemistry > [noun] > molecules > other molecules supermolecule1834 open chain1880 excimer1960 exciplex1966 superatom1972 1966 M. Walker et al. in Jrnl. Chem. Physics 3456/1 The results appear to confirm the existence of 1:2 excited complex states, which we have termed exciplex states, for both solutes. 1972 C. H. DePuy & O. L. Chapman Molecular Reactions & Photochem. iv. 50 It is probable that the reaction involves an exciplex..that collapses to the biradical. 1976 K. Davis in R. Foster Molecular Association I. iii. 187 For systems in which no ground-state complex formation is detectable, formation of a complex is possible between an excited donor (or acceptor) and a ground-state acceptor (or donor)... Such a complex has been termed..an ‘exciplex’ or excited state complex and is similar to the complex formed between an excited-state molecule and a ground-state molecule of the same species termed an excimer. 1984 Science 23 Nov. 917/1 Electronically excited molecules, being better electron donors and acceptors than their ground states, form charge-transfer complexes (exciplexes) which can lead to radical ions. Exciplex emission is widely used to probe polymers and organized media such as membranes and micelles. This entry has not yet been fully updated (first published 1989; most recently modified version published online June 2018). < n.1966
随便看	franco-negroid franco-prussian franco-roman francoamerican francocanadian francogallican francogauls francogerman francoirish francoism francoist francolin francolin partridge francolins francolite francomania francomaniac franconegroid franconian francophil francophile francophiles francophilia francophils francophobe