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单词 1,10-phenanthroline
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1,10-phenanthroline
Each of a number of isomeric, crystalline, heteroaromatic compounds having the formula C12H8N2, whose molecules have a tricyclic phenanthrene ring system in which one CH group in each of the two outer rings is replaced by a nitrogen atom; esp. (in full 1,10-phenanthroline), the ortho isomer, which is used as an indicator for iron, with which it forms a red-orange complex.
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phenanthroline1882
1882 Jrnl. Chem. Soc. 42 1111 Phenanthroline,..obtained by the action of glycerol and sulphuric acid on metadiamidobenzene, crystallises in transparent plates (m.p. 79°).
1909 Chem. Abstr. 3 2571 The terms o-, m- and p-phenanthroline are suggested in place of isophenanthroline, phenanthroline and pseudophenanthroline.
1966 McGraw-Hill Encycl. Sci. & Technol. (rev. ed.) IV. 273/1 Certain organic compounds, such as 1,10-phenanthroline, also catalyze the drying of oils and have been used for this purpose.
1978 Sci. Amer. July 120/2 After the bromine color disappears mix in one milliliter of ·025-molar phenanthroline ferrous sulfate (a dye sometimes called ferroin).
1991 D. T. Sawyer Oxygen Chem. iv. 87 (table) Product solution..assayed for residual Fe(II) by MnO4 titration and by colorimetry with 1,10-o-phenanthroline.
2004 Tetrahedron Lett. 45 7806/1 The large variety of complexes based on phenanthroline..derivatives allows the formation of many different molecular systems with various applications.
extracted from phenanthrolinen.
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