单词 | fenchane |
释义 | fenchanen. Chemistry. A liquid that is chemically a saturated bicyclic hydrocarbon of the terpene series, C10H18, and may be considered the parent compound of a series including the fenchenes and fenchone; also applied to some related isomers of this (see quot. 19491). ΘΚΠ the world > matter > chemistry > organic chemistry > hydrocarbons > [noun] > terpenes > others citrene1834 citronyl1836 camphene1839 terebenthene1857 terebilene1857 thymene1857 sylvestrene1877 cinene1884 pinene1885 fenchene1891 phellandrene1893 camphane1895 humulene1895 myrcene1895 sabinene1900 limonene1901 terpinene1902 terpinolene1902 fenchane1907 1907 Jrnl. Chem. Soc. 92 i. 24 The close relationship of camphane and fenchane. 1949 J. L. Simonsen & L. N. Owen Terpenes (ed. 2) II. vi. 528 By the catalytic hydrogenation of α-fenchene..Zelinski [1904] prepared a saturated hydrocarbon, C10H18, to which he gave the name fenchane... In 1911 Wolff and Kishner prepared from fenchonehydrazone an isomeric hydrocarbon having completely different properties... This hydrocarbon was designated fenchane, whilst for Zelinski's hydrocarbon the name isobornylane was adopted. [Note]isoBornylane is also termed α-fenchane. 1949 J. L. Simonsen & L. N. Owen Terpenes (ed. 2) II. vi. 530 On reduction..it [sc. isobornylol] does not give isobornylane, but a hydrocarbon..termed β-fenchane. 1953 Eastman & Noller in H. Gilman Org. Chem. IV. vii. 656 The most important naturally occurring terpene having the fenchane carbon skeleton is fenchone. This entry has not yet been fully updated (first published 1972; most recently modified version published online June 2018). < n.1907 |
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