单词 | idryl |
释义 | idryln. Chemistry. Obsolete exc. Historical. (a) A mixture of fluoranthene and other hydrocarbons (see quot. 1952) originally obtained from the mercury ores of Idrija, in north-west Yugoslavia (now Slovenia), and thought to be a single compound. (b) = fluoranthene n. ΘΚΠ the world > matter > chemistry > organic chemistry > chemicals from tar > [noun] naphthalene1821 idryl1845 picoline1846 fluorene1867 fluoranthene1878 isoquinoline1886 indene1888 the world > matter > chemistry > organic chemistry > hydrocarbons > [noun] > hydrocarbon mixtures idryl1845 naphtha1846 tetrahydronaphthalene1887 Tetralin1920 synthol1924 1845 C. Bödeker in Chem. Gaz. 15 Feb. 73 One of the products obtained in the working of the bituminous mercurial ores in Idria is the so-called Stupp, a soft black mass mixed with globules of mercury. It was supposed to contain idrialine, but in its stead another hydrocarbon was found, idryle C3H, and a more accurate examination has proved that idrialine..is an oxide of idryle. 1863 Fownes's Man. Elem. Chem. (ed. 9) 698 Idrialin..is generally associated with a hydrocarbon idryl. 1866 H. Watts tr. L. Gmelin Hand-bk. Chem. XVII. 477 Idryl. C42H14... The crystals are nearly colourless, with a tinge of yellowish-green... Idryl assumes a golden-yellow colour in cold oil of vitriol. 1877 Chem. News 16 Nov. 222/2 G. Goldschmidt, ‘Idryl’. This body, found by Bödeker in Idria, is ascertained to consist of several hydrocarbons... Besides chrysen, pyren, anthracen, phenanthren, a new hydrocarbon, C15H10, was isolated, and receives the name originally applied to the mixture. 1892 H. E. Roscoe & C. Schorlemmer Treat. Chem. (new ed.) III. vi. 523 Fluoranthene, C15H10, is found in coal-tar, and is also identical with idryl, one of the constituents of ‘stuppfett’. 1926 H. G. Rule tr. J. Schmidt Text-bk. Org. Chem. ii. xvii. 513 Fluoranthene or Idryl, m.p. 110°, b.p. 250° (at 60 mm.). 1952 Chem. Rev. 50 483 In 1844 Boedeker..distilled these ores, with production of a similar hydrocarbon which he named idryl. Much later Goldschmiedt..showed..that idryl consisted of anthracene, phenanthrene, chrysene, pyrene, and a hitherto unknown hydrocarbon, C15H10, to which he gave the name idryl. Simultaneously with Goldschmiedt's discovery, Fittig and Gebhard..isolated..a hydrocarbon which was named fluoranthene and was claimed to be identical with Goldschmiedt's idryl. This entry has not yet been fully updated (first published 1933; most recently modified version published online June 2019). < n.1845 |
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