单词 | imino- |
释义 | imino-comb. form Chemistry. 1. Combining form of imine n.; also used attributively (without hyphen) as quasi- adj. a. imino-chloride n. Brit. /ɪˌmiːnəʊˈklɔːrʌɪd/ , U.S. /ᵻˌminoʊˈklɔˌraɪd/ , /ˌɪmənoʊˈklɔˌraɪd/ ΚΠ 1900 Jrnl. Chem. Soc. 78 i. 295 The authors think it probable that aliphatic substituted imino-chlorides of aromatic acids are readily decomposed into alkyl chlorides and aromatic nitriles or their polymerides. imino-compound n. Brit. /ɪˌmiːnəʊˈkɒmpaʊnd/ , U.S. /ᵻˌminoʊˈkɑmˌpaʊnd/ , /ˌɪmənoʊˈkɑmˌpaʊnd/ ΚΠ 1904 Jrnl. Chem. Soc. 85 1726 (heading) The formation and reactions of imino-compounds. 1924 C. Hollins Synthesis Nitrogen Ring Compounds vii. 203 The yield of imino-compound..was very small. iminosulphonic acid n. Brit. /ɪˌmiːnəʊsʌlˌfɒnɪk ˈasɪd/ , U.S. /ᵻˈˌminoʊsəlˌfɑnɪk ˈæsəd/ , /ˈˌɪmənoʊsəlˌfɑnɪk ˈæsəd/ ΚΠ 1896 Jrnl. Chem. Soc. 70 ii. Index 911/1 Iminosulphonic acid. b. imino-acid n. Brit. /ɪˌmiːnəʊˈasɪd/ , U.S. /ᵻˌminoʊˈæsəd/ , /ˌɪmənoʊˈæsəd/ any organic acid that contains an imino-group; also (now rare), an imidic acid.ΘΚΠ the world > matter > chemistry > organic chemistry > organic acids > [noun] > imino acids imino-acid1903 1903 Jrnl. Chem. Soc. 84 i. 692 The formation and properties of some iminoacid anhydrides of the type of the hypothetical iminoformic anhydride, NH:CH·O·CH:O. 1907 Jrnl. Chem. Soc. 92 i. 393 Mechanism of the Reaction in the Formation of α-Amino- and Imino-acids. 1937Imino-acid [see imino-ester n.]. 1953 J. S. Fruton & S. Simmonds Gen. Biochem. iii. 49 The hydrolysis of a protein leads to the formation of a variety of amino acids... The compounds having the general formula shown are termed α-amino acids, whereas proline and hydroxyproline are more correctly designated α-imino acids; for convenience, however, these two cyclic compounds are also called amino acids. 1961 Jrnl. Clin. Investig. 40 i. 843/1 Since nearly all of the hydroxyproline of the body is found in collagen, it has been suggested..that the urinary excretion of the imino acid may be an important index of collagen metabolism. 1967 New Scientist 24 Aug. 375/1 The precise proportion of the imino-acid hydroxyproline in the important protein collagen. imino-ester n. Brit. /ɪˌmiːnəʊˈɛstə/ , U.S. /ᵻˌminoʊˈɛstər/ , /ˌɪmənoʊˈɛstər/ (also imino-ether) any compound that contains C(NH)OR and is consequently an ester of an imidic acid; more correctly called an imido-ester.ΘΚΠ the world > matter > chemistry > organic chemistry > esters > [noun] > named oxalic ether1788 margarate1819 acrylate1843 urethane1856 tropeine1880 malonic ester1881 heavy oil of wine1882 phosphatide1884 ethanoate1892 imino-ester1897 acetylcholine1906 phaeophytin1907 phytic acid1908 propiolactone1917 silicon ester1923 methyl methacrylate1933 Tylose1934 testosterone propionate1937 filicin1941 trichothecin1948 siphonein1949 acetyl coenzyme A1950 acetyl CoA1951 1897 Jrnl. Chem. Soc. 62 ii. Index 804/2 Imino-ethers. 1908 Jrnl. Chem. Soc. 94 i. 419 The catalysis of imino-esters. 1908 Jrnl. Chem. Soc. 94 i. 419 The imino-esters were prepared by a modification of Pinner's method... The velocity of reaction of the free imino-esters in aqueous solution have been determined and the results are tabulated. 1935 H. J. Lucas Org. Chem. xxi. 314 In the presence of anhydrous hydrogen chloride, nitriles add alcohols to form imino esters: CH3C≡N + HOC2H5→CH3CNHOC2H5. 1937 T. W. J. Taylor & W. Baker Sidgwick's Org. Chem. Nitrogen (rev. ed.) v. 154 The imino-ethers, which can also be regarded as esters of imino-acids and are sometimes called imino-esters have the general formula R·C(OR′): NH. 1951 C. R. Noller Chem. Org. Compounds xiii. 242 The corresponding O-alkyl derivatives, RNHC—OR, are known and are called imido esters (less correctly imino esters or imido ethers). imino-group n. Brit. /ɪˈmiːnəʊɡruːp/ , U.S. /ᵻˈminoʊˌɡrup/ , /ˈɪmənoʊˌɡrup/ the group NH as it occurs in imines (in quot. 1906 it denotes what is more correctly called an imido-group).ΘΚΠ the world > matter > chemistry > organic chemistry > imides or imines > [noun] > imino-group imino-group1906 1906 Jrnl. Chem. Soc. 89 ii. 1837 The members of the former class contain the grouping CONH·CO·NH·CO·, whereas in no member of the latter class is this grouping present... Each of the imino-groups contained in the above-mentioned grouping, being connected with two carbonyl groups, will be possessed of acidic properties. 1966 T. Z. Nowakowski & A. J. Clarke tr. V. Kretovich Princ. Plant Biochem. (ed. 4) i. 16 Proline, strictly speaking, is not an amino acid, as it contains an imino group (NH). 2. Examples of the general use (without hyphen) as quasi-adj. ΚΠ 1901 Proc. Chem. Soc. 17 61 A liquid base of ‘imino’ odour. 1937 F. C. Whitmore Org. Chem. i. 226 This product loses water to form the imino analog of formaldehyde, H2CNH. This entry has not yet been fully updated (first published 1976; most recently modified version published online March 2022). < comb. form1896 |
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