单词 | ketimine |
释义 | > as lemmasketimine ketimine n. Brit. /ˈkiːtᵻmiːn/ , U.S. /ˈkidᵻˌmin/ any compound containing the grouping C=NH, formed e.g. by the action of ammonia on a ketone.ΚΠ 1909 J. F. Thorpe in Proc. Chem. Soc. 25 309 It is suggested that as the compounds containing the group C:NH are in many respects analogous to the ketones, the general name ketimine should be applied to them, leaving the name imine to be applied to the secondary amines. 1938 C. F. H. Allen & A. H. Blatt in H. Gilman Org. Chem. I. vi. 568 Monomolecular ketimines..have been prepared; they too are readily hydrolyzed and reduced. 1971 N. L. Allinger et al. Org. Chem. xxi. 586 Grignard reagents add to the cyano group of most nitriles to give salts of ketimines. < as lemmas |
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