metalatev.

Brit.

/ˈmɛtəleɪt/, U.S.

/ˈmɛdəˌleɪt/

Forms: 1900s– metalate, 1900s– metallate.

Origin: Formed within English, by derivation. Etymons: metal n., -ate suffix³.

Etymology: < metal n. + -ate suffix³, after metalation n.

Chemistry.

transitive. To bring about metalation in (a compound); to subject (a compound) to metalation.

ΘΚΠ

the world > matter > chemistry > organic chemistry > organometallurgy > metalation [verb (transitive)]

metalate1939

1939 Jrnl. Amer. Chem. Soc. 61 109/2 Phenyl ether was not metalated by triphenylmethylsodium.

1954 Org. Reactions 8 vi. 260 n-Butyllithium metalates thiophene in the 2 position.

1989 tr. C. Elschenbroich & A. Salzer Organometallics v. 33 Ethers are slowly metallated at the α-position.

Derivatives

ˈmetalated adj.

ΘΚΠ

the world > matter > chemistry > organic chemistry > organometallurgy > [adjective] > metalation

metalated1954

1954 Org. Reactions 8 vi. 261 The usual metalating agents..yield volatile acids which are easily separated from the acids of higher molecular weight obtained from the metalated products themselves.

1992 Organometallics 11 79/1 The metalated species was formed in 20 h in the presence of sodium acetate.

ˈmetalating adj.

ΚΠ

1954 Org. Reactions 8 vi. 261 The usual metalating agents..yield volatile acids which are easily separated from the acids of higher molecular weight obtained from the metalated products themselves.

1966 McGraw-Hill Encycl. Sci. & Technol. (rev. ed.) IX. 402/2 The most commonly used ‘metalating agent’..is n-butyllithium in ether solution.

1992 Organometallics 11 1412/1 As a result, we selected lithium diisopropylamide (LDA) as the best metalating agent.

This entry has been updated (OED Third Edition, December 2001; most recently modified version published online March 2022).

单词	metalate
释义	metalatev. Brit. /ˈmɛtəleɪt/, U.S. /ˈmɛdəˌleɪt/ Forms: 1900s– metalate, 1900s– metallate. Origin: Formed within English, by derivation. Etymons: metal n., -ate suffix³. Etymology: < metal n. + -ate suffix³, after metalation n. Chemistry. transitive. To bring about metalation in (a compound); to subject (a compound) to metalation. ΘΚΠ the world > matter > chemistry > organic chemistry > organometallurgy > metalation [verb (transitive)] metalate1939 1939 Jrnl. Amer. Chem. Soc. 61 109/2 Phenyl ether was not metalated by triphenylmethylsodium. 1954 Org. Reactions 8 vi. 260 n-Butyllithium metalates thiophene in the 2 position. 1989 tr. C. Elschenbroich & A. Salzer Organometallics v. 33 Ethers are slowly metallated at the α-position. Derivatives ˈmetalated adj. ΘΚΠ the world > matter > chemistry > organic chemistry > organometallurgy > [adjective] > metalation metalated1954 1954 Org. Reactions 8 vi. 261 The usual metalating agents..yield volatile acids which are easily separated from the acids of higher molecular weight obtained from the metalated products themselves. 1992 Organometallics 11 79/1 The metalated species was formed in 20 h in the presence of sodium acetate. ˈmetalating adj. ΚΠ 1954 Org. Reactions 8 vi. 261 The usual metalating agents..yield volatile acids which are easily separated from the acids of higher molecular weight obtained from the metalated products themselves. 1966 McGraw-Hill Encycl. Sci. & Technol. (rev. ed.) IX. 402/2 The most commonly used ‘metalating agent’..is n-butyllithium in ether solution. 1992 Organometallics 11 1412/1 As a result, we selected lithium diisopropylamide (LDA) as the best metalating agent. This entry has been updated (OED Third Edition, December 2001; most recently modified version published online March 2022). < v.1939
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