单词 | non-stoichiometric |
释义 | non-stoichiometricadj. Chemistry. Containing or representing atoms of the different elements in numbers that do not bear a simple integral ratio to one another or are not in the ratio expected from an ideal formula. ΘΚΠ the world > matter > chemistry > chemical properties > [adjective] > of or relating to miscellaneous other properties sweet1666 nimble1671 watery1741 unvitriolized1757 greedy1758 unneutralized1758 unvitrifiable1758 free1783 fixed1800 nascent1800 inorganic1831 assimilative1837 unnitrogenized1846 inactive1848 kaligenous1854 unacceptant1866 aggressive1888 oligodynamic1893 chromotropic1899 undissociated1899 osmophoric1901 thermochromic1904 unary1923 non-stoichiometric1943 odoriphoric1944 slow-release1946 sonoluminescent1961 uniaxial1965 1943 Proc. Royal Soc. A. 184 84 The potential quadrivalency of the metal should favour the formation of non-stoichiometric stannous chloride. 1965 C. S. G. Phillips & R. J. P. Williams Inorg. Chem. I. viii. 267 There are compounds of the type Fe0·95O, GeTe1·025, Ti1·103S2. Such non-stoicheiometric compounds are found largely amongst minerals, alloys, and those compounds which contain..elements giving rise to at least two valence states. 1988 F. A. Cotton & G. Wilkinson Adv. Inorg. Chem. (ed. 5) iii. 121 Titanium, zirconium, and hafnium absorb hydrogen exothermically to give nonstoichiometric materials such as TiH1.7 and ZrH1.9. 2001 Water Res. 35 1534 Initial concentrations of Fe( ii) and Cr( vi) were 50 and 20 μM, respectively, representing a deficient amount of Fe( ii) (i.e. nonstoichiometric conditions). This entry has been updated (OED Third Edition, December 2003; most recently modified version published online March 2022). < |
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