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单词 non-stoichiometric
释义

non-stoichiometricadj.

Brit. /ˌnɒnstɔɪkɪəˈmɛtrɪk/, U.S. /ˌnɑnˌstɔɪkioʊˈmɛtrɪk/
Forms: 1900s– non-stoicheiometric, 1900s– non-stoichiometric.
Origin: Formed within English, by derivation. Etymons: non- prefix, stoicheiometric adj. at stoicheiometry n. Derivatives
Etymology: < non- prefix + stoicheiometric adj. at stoicheiometry n. Derivatives.
Chemistry.
Containing or representing atoms of the different elements in numbers that do not bear a simple integral ratio to one another or are not in the ratio expected from an ideal formula.
ΘΚΠ
the world > matter > chemistry > chemical properties > [adjective] > of or relating to miscellaneous other properties
sweet1666
nimble1671
watery1741
unvitriolized1757
greedy1758
unneutralized1758
unvitrifiable1758
free1783
fixed1800
nascent1800
inorganic1831
assimilative1837
unnitrogenized1846
inactive1848
kaligenous1854
unacceptant1866
aggressive1888
oligodynamic1893
chromotropic1899
undissociated1899
osmophoric1901
thermochromic1904
unary1923
non-stoichiometric1943
odoriphoric1944
slow-release1946
sonoluminescent1961
uniaxial1965
1943 Proc. Royal Soc. A. 184 84 The potential quadrivalency of the metal should favour the formation of non-stoichiometric stannous chloride.
1965 C. S. G. Phillips & R. J. P. Williams Inorg. Chem. I. viii. 267 There are compounds of the type Fe0·95O, GeTe1·025, Ti1·103S2. Such non-stoicheiometric compounds are found largely amongst minerals, alloys, and those compounds which contain..elements giving rise to at least two valence states.
1988 F. A. Cotton & G. Wilkinson Adv. Inorg. Chem. (ed. 5) iii. 121 Titanium, zirconium, and hafnium absorb hydrogen exothermically to give nonstoichiometric materials such as TiH1.7 and ZrH1.9.
2001 Water Res. 35 1534 Initial concentrations of Fe( ii) and Cr( vi) were 50 and 20 μM, respectively, representing a deficient amount of Fe( ii) (i.e. nonstoichiometric conditions).
This entry has been updated (OED Third Edition, December 2003; most recently modified version published online March 2022).
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adj.1943
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