单词 | phospham |
释义 | phosphamn. Chemistry. A white to reddish polymeric solid, (NPNH)n, first obtained by the reaction of phosphoric acid with ammonia. ΚΠ 1849 H. Watts tr. L. Gmelin Hand-bk. Chem. II. xii. 440 The residue..whose composition is expressed by the formula PHN2..Gerhardt calls Phospham. 1877 H. Watts Dict. Chem. IV. 497 Phospham..is a bulky powder, white if moisture has been carefully excluded during its preparation, reddish in the contrary case. 1962 Chem. Rev. 62 266/2 Phosphams containing phenyl groups have been prepared by the thermal decomposition of anilinophosphazenes. 1994 Eos 75 xliv. Suppl. 662/2 At ambient conditions the phosphorus nitride amide phospham (PNNH) has a cristobalite-like structure. This entry has been updated (OED Third Edition, March 2006; most recently modified version published online March 2022). < n.1849 |
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