phosphazinen.

Brit.

/ˈfɒsfəziːn/, U.S.

/ˈfɑsfəˌzin/

Origin: Formed within English, by compounding; modelled on a German lexical item. Etymons: phospho- comb. form, azine n.

Etymology: < phospho- comb. form + azine n., after German Phosphazin (H. Staudinger & J. Meyer, in Helvetica chimica acta 2 (1919) 619).

Chemistry.

Any compound containing an azine group =N—N= bonded directly to a phosphorus atom. Cf. phosphazene n.

ΚΠ

1920 Jrnl. Chem. Soc. 118 105 Tertiary phosphines combine more or less readily with the most varied aliphatic diazo-compounds, yielding derivatives, for which the name phosphazines is proposed, in accordance with the scheme CR₂:N⋮N + PR₃ → R₂C:N—N:PR₃.

1958 J. R. Van Wazer Phosphorus & its Compounds I. vi. 341 The compound (C₆H₅)₃PNN=C(C₆H₅)₂, a typical phosphazine, is a yellow, stable solid with slightly basic properties.

1999 Acta Crystallographica C. 55 1017/1 The synthetic utility of phosphazines (R₃P=N—N=CR₂) has been recognized for many years.

This entry has been updated (OED Third Edition, March 2006; most recently modified version published online March 2022).

单词	phosphazine
释义	phosphazinen. Brit. /ˈfɒsfəziːn/, U.S. /ˈfɑsfəˌzin/ Origin: Formed within English, by compounding; modelled on a German lexical item. Etymons: phospho- comb. form, azine n. Etymology: < phospho- comb. form + azine n., after German Phosphazin (H. Staudinger & J. Meyer, in Helvetica chimica acta 2 (1919) 619). Chemistry. Any compound containing an azine group =N—N= bonded directly to a phosphorus atom. Cf. phosphazene n. ΚΠ 1920 Jrnl. Chem. Soc. 118 105 Tertiary phosphines combine more or less readily with the most varied aliphatic diazo-compounds, yielding derivatives, for which the name phosphazines is proposed, in accordance with the scheme CR₂:N⋮N + PR₃ → R₂C:N—N:PR₃. 1958 J. R. Van Wazer Phosphorus & its Compounds I. vi. 341 The compound (C₆H₅)₃PNN=C(C₆H₅)₂, a typical phosphazine, is a yellow, stable solid with slightly basic properties. 1999 Acta Crystallographica C. 55 1017/1 The synthetic utility of phosphazines (R₃P=N—N=CR₂) has been recognized for many years. This entry has been updated (OED Third Edition, March 2006; most recently modified version published online March 2022). < n.1920
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