单词 | phospho- |
释义 | phospho-comb. form Forming terms in Chemistry, Mineralogy, etc., denoting substances containing phosphorus or phosphates, or (in Biochemistry) involved in the metabolism of phosphates. phosphocozymase n. Brit. /ˌfɒsfə(ʊ)kə(ʊ)ˈzʌɪmeɪz/ , U.S. /ˌfɑsfoʊˌkoʊˈzaɪˌmeɪs/ , /ˌfɑsfoʊˌkoʊˈzaɪˌmeɪz/ Biochemistry (disused) the coenzyme NADP (nicotinamide adenine dinucleotide phosphate).ΚΠ 1946 Nature 24 Aug. 275/2 It was found with a preparation of cozymase and phosphocozymase received from Prof. Otto Warburg that only one pentose was found for two phosphorus atoms. 1964 M. Florkin & E. H. Stotz Comprehensive Biochem. (rev. ed.) XIII. vii. 41 The names ‘cozymase’, ‘phosphocozymase’..should no longer be used. phosphocreatine n. Brit. /ˌfɒsfə(ʊ)ˈkriːətiːn/ , /ˌfɒsfə(ʊ)ˈkriːətɪn/ , U.S. /ˌfɑsfoʊˈkriəˌtin/ , /ˌfɑsfoʊˈkriədən/ Biochemistry creatine phosphate, CH2(COOH)N(CH3)C(NH)NHPO(OH)2, the phosphagen of vertebrate muscle.ΘΚΠ the world > matter > chemistry > organic chemistry > organic salts > [noun] > miscellaneous others alum zucarinea1425 white precipitate1588 volatile salt or salts1639 malate1788 oxalate1788 sebate1788 succinate1789 camphorate1800 suberate1800 tannate1802 formate1807 zymate1817 uranate1819 ambreate1820 fungate1821 hydriodide1823 sorbate1823 fulminate1824 uraniate1824 pinate1829 oleate1831 pectate1831 resinate1831 xanthate1831 formobenzoate1834 racemate1835 indigotate1838 japonate1838 oxalhydrate1838 oxalovinate1838 palmate1838 pyruvate1838 roccellate1838 rubinate1838 verdite1838 oxalurate1839 sesquisalt1839 palmitate1840 rhabarbarate1840 hippurate1841 palmitin1841 sericate1841 stearate1841 oenanthylate1843 humate1844 parabanate1844 urethylane1844 angelate1846 fungiate1847 nitroprusside1849 sodium nitroprusside1849 fulminurate1855 igasurate1855 inosinate1855 phenate1857 sinapate1857 styphnate1857 anchoate1858 parellate1858 toluate1860 piperate1862 fumarate1864 glycollate1864 hydurilate1865 hyoglycocholate1865 isamates1865 itaconates1865–72 paralactate1866 porphyrate1866 usnate1866 thebolactate1867 oxalonitrate1868 rhodanate1868 stearerate1868 terebate1868 terephthalate1868 thymotate1868 turpetholate1868 violurate1868 viridate1868 xanthide1868 glycocholate1872 xylate1872 xylidate1872 tiglate1875 peptonate1876 hydracrylate1877 thymolate1880 formamidine1882 carboxylate1884 nucleate1896 phytin1905 cacodylate1908 cupferron1910 protamine sulphate1915 metallic soap1918 pentaerythritol tetranitrate1923 phosphagen1927 phosphocreatine1927 viologen1933 pentachlorophenate1938 hyaluronate1946 tetraethylpyrophosphate1947 pteroylglutamate1948 inosate- 1927 C. H. Fiske & Y. Subbarow in Science 22 Apr. 402/2 Our main evidence for the existence of ‘phosphocreatine’ in muscle is of a quite different nature. 1950 G. A. Baitsell Human Biol. (ed. 2) xiv. 243 The energy for the resynthesis of phosphocreatine, following contraction, comes indirectly from the oxidation of glucose in the muscle cells. 1990 Jrnl. Developmental Physiol. 14 3/1 We previously reported that increases in the ATP and phosphocreatine contents occur in the first hour of extrauterine life. phosphoferrite n. Brit. /ˌfɒsfə(ʊ)ˈfɛrʌɪt/ , U.S. /ˌfɑsfoʊˈfɛˌraɪt/ [after German Phosphoferrit (H. Laubmann & H. Steinmetz 1920, in Zeitschr. f. Krystallogr. u. Min. 55 569)] Mineralogy a mineral consisting of a hydrated phosphate of iron (usually partly replaced by manganese), Fe3(PO4)2.3H2O, which occurs as pale green crystals and forms an isomorphous series with reddingite.ΘΚΠ the world > the earth > minerals > types of mineral > phosphates > [noun] > iron or manganese phosphates hureaulite1831 heterosite1834 triplite1850 zwieselite1861 reddingite1878 triploidite1878 purpurite1905 stewartite1912 phosphoferrite1921 landesite1930 rockbridgeite1949 wolfeite1949 kryzhanovskite1951 strunzite1958 switzerite1967 1921 Mineral. Abstr. 1 125 Phosphoferrite from Hagendorf, as cloudy-white or greenish, crystalline masses with greasy lustre; H[ardness] 4–5, sp. gr. 3·156. 1974 Nature 27 Sept. 305/2 The evidence clearly points to a complete solid solution series between Fe32+(H2O)3[PO4]2 (phosphoferrite) and Fe33+(OH)3[PO4]2 (kryzhanovskite). 1984 Amer. Mineralogist 69 209/1 Garyansellite is a unique species, a Mg-dominant member of the phosphoferrite group. phosphofructokinase n. Brit. /ˌfɒsfə(ʊ)frʊktə(ʊ)ˈkʌɪneɪz/ , /ˌfɒsfə(ʊ)frʌktə(ʊ)ˈkʌɪneɪz/ , U.S. /ˌfɑsfoʊˌfrʊktoʊˈkaɪˌneɪs/ , /ˌfɑsfoʊˌfrʊktoʊˈkaɪˌneɪz/ , /ˌfɑsfoʊˌfrəktoʊˈkaɪˌneɪs/ , /ˌfɑsfoʊˌfrəktoʊˈkaɪˌneɪz/ Biochemistry an enzyme which brings about the irreversible transfer of a phosphate group from ATP to fructose phosphate in glycolysis (abbreviated PFK).ΚΠ 1947 Federation Proc. (Federation Amer. Soc. Exper. Biol.) 6 297 (heading) The purification of phosphofructokinase from rabbit muscle. 1970 E. J. Ambrose & D. M. Easty Cell Biol. xiii. 246 Fructose-6-phosphate is phosphorylated by ATP to form fructose-1,6-diphosphate in a reaction catalyzed by a specific phosphofructokinase. 1999 Gun Dog Dec. 46/2 American cockers and English springers can be tested for the gene that causes phosphofructokinase deficiency. phosphoglucomutase n. Brit. /ˌfɒsfə(ʊ)ɡluːkə(ʊ)ˈmjuːteɪz/ , U.S. /ˌfɑsfoʊˌɡlukoʊˈmjuˌteɪs/ , /ˌfɑsfoʊˌɡlukoʊˈmjuˌteɪz/ Biochemistry an enzyme which brings about the conversion of one isomeric form of glucose phosphate to another by changing the position of the phosphate group.ΚΠ 1938 G. T. Cori et al. in Jrnl. Biol. Chem. 124 543 A study of the enzyme which causes a migration of the phosphate group from carbon atom 1 to the spacially [sic] adjacent carbon atom 6; the enzyme will be referred to as phospho~glucomutase. 1964 A. White et al. Princ. Biochem. (ed. 3) xxi. 403 The best-studied mutase is phosphoglucomutase, which has been obtained in pure form from rabbit muscle, yeast, and several bacterial species. 2002 Biochemistry 41 8351 Two classes of phosphoglucomutases (alpha-PGM and beta-PGM) are distinguished on the basis of their specificity for alpha- and beta-glucose-1-phosphate. phosphogypsum n. Brit. /ˌfɒsfə(ʊ)ˈdʒɪps(ə)m/ , U.S. /ˌfɑsfoʊˈdʒɪpsəm/ an impure form of gypsum, contaminated mainly with phosphate, which is a by-product of the industrial production of orthophosphoric acid from phosphate rock.ΘΚΠ society > occupation and work > materials > raw material > mineral material > [noun] > gypsum > type of terra alba1871 phosphogypsum1954 1954 Industr. & Engin. Chem. 46 453/1 The regeneration of sulfuric acid from the by-product calcium sulfate, called phosphogypsum. 1983 New Scientist 16 June 760/1 Yellow sludge (phosphogypsum) is produced when phosphate rock is treated with sulphuric acid to make fertiliser. 2001 S. Roaf et al. Ecohouse (2002) vi. 141 It must be natural gypsum, not phosphogypsum, which is radioactive. phosphoinositide n. Brit. /ˌfɒsfəʊᵻˈnəʊsᵻtʌɪd/ , /ˌfɒsfəʊʌɪˈnəʊsᵻtʌɪd/ , U.S. /ˌfɑsfoʊaɪˈnoʊsəˌtaɪd/ Biochemistry any phospholipid in which the phosphate group is linked to an inositol residue.ΚΠ 1946 J. Folch in Federation Proc. (Federation Amer. Soc. Exper. Biol.) 5 134/1 (title) Isolation of brain diphosphoinositide, a new phosphatide containing inositol meta diphosphate.] 1948 J. Folch & W. M. Sperry in Ann. Rev. Biochem. 17 148 The reviewers advise against the further use of the terms lecithin, cephalin, and sphingomyelin..and propose the adoption of the names..‘phosphoglycerides’, ‘phosphoinositides’, and ‘phosphosphingosides’. 1971 D. G. Bishop in A. R. Johnson & J. B. Davenport Biochem. Lipids xx. 411 Although phosphoinositides have been recognized as important constituents of brain lipids for some time, their occurrence in nature is now known to be widespread. 1990 EMBO Jrnl. 9 3907/1 The turnover of different phospholipids, like phosphoinositide (PI) or phosphatidylcholine (PC), has been implicated in the cascades activated by mitogens. phosphokinase n. Brit. /ˌfɒsfə(ʊ)ˈkʌɪneɪz/ , U.S. /ˌfɑsfoʊˈkaɪˌneɪs/ , /ˌfɑsfoʊˈkaɪˌneɪz/ Biochemistry an enzyme which transfers a phosphate group from ATP to another molecule (esp. creatine); = kinase n. b.ΘΚΠ the world > life > biology > biological processes > genetic activity > genetic components > [noun] > nucleic acid > enzymes galactase1898 cellulase1901 nuclease1902 xanthine oxidase1905 exoenzyme1908 glucosidase1909 galactase1910 nucleosidase1911 nucleotidase1911 adenosine deaminase1913 cellobiase1919 hydratase1922 activase1928 hexokinase1930 histaminase1930 kallikrein1930 Michaelis constant1930 cholinesterase1932 phosphodiesterase1932 chymotrypsin1933 glycosidase1933 rhodanese1933 acetylcholinesterase1937 prolidase1937 diaphorase1938 aconitase1939 hyaluronidase1940 transaminase1940 hydrase1943 isomerase1943 lactoperoxidase1943 streptokinase1944 pectinesterase1945 pectinmethylesterase1945 phosphokinase1946 alliinase1947 CoA1947 phosphotransferase1948 polymerase1948 transferase1948 elastase1949 amyloglucosidase1950 transacetylase1950 transhydrogenase1952 hydroxylase1953 kinase1953 transketolase1953 synthase1954 hexosaminidase1955 translocase1957 angiotensinase1958 angiotensin converting enzyme1960 photoenzyme1960 acetyltransferase1961 adenyl cyclase1961 adenylate cyclase1962 replicase1962 ADA1963 transcriptase1963 adenylyl cyclase1964 recombinase1964 laminarinase1966 nickase1967 acrosin1970 reverse transcriptase1970 cellobiohydrolase1972 cyclooxygenase1974 laminaranase1974 primase1977 helicase1978 monodeiodinase1978 transposase1979 maturase1980 1946 M. Dixon & D. M. Needham in Nature 28 Sept. 435/1 Needham has given reasons for believing that the component of the pyruvate oxidase system which is inhibited may be a phosphate-transferring enzyme belonging to the same group as hexokinase. We suggested the name ‘phosphokinase’ for this small but important group of enzymes. 1953 Brit. Med. Bull. 9 110/2 The phosphokinases all seem to have the common property that they require the presence of Mg++ for their activity. 1990 Nucleic Acids Res. 18 256/2 Approximately 1 × 107 nuclei were added to transcription buffer containing..100 μg/ml creatine phosphokinase. phosphomolybdate n. Brit. /ˌfɒsfə(ʊ)məˈlɪbdeɪt/ , U.S. /ˌfɑsfoʊməˈlɪbˌdeɪt/ Chemistry a salt of phosphomolybdic acid; an anion containing phosphorus together with several molybdenum and oxygen atoms, esp. PMo12O403−.ΚΠ 1856 W. A. Miller Elements Chem. II. 783 The Phosphomolybdate of Soda is an extremely delicate test for the presence of salt of ammonium in solution. 1922 T. M. Lowry Inorg. Chem. xxxix. 747 Ammonium phosphomolybdate, (NH4)3PO4,10MoO3,..dissolves readily in aqueous ammonia, or when an excess of phosphoric acid is present. 1965 C. S. G. Phillips & R. J. P. Williams Inorg. Chem. I. xiv. 538 In recent years a large number of mixed polyanions have been prepared and studied. The best known examples are the phosphomolybdates which are used to precipitate phosphorus from solution. 1989 Nature 8 June 461/1 Arsenate..combines with molybdate to form a heteropolyacid with a molar absorptivity equal to that of the phosphomolybdate complex in the standard analytical phosphate technique. phosphomolybdic adj. Brit. /ˌfɒsfə(ʊ)məˈlɪbdɪk/ , U.S. /ˌfɑsfoʊməˈlɪbdɪk/ Chemistry phosphomolybdic acid, a complex acid, H3PMo12O40, bright yellow salts of which are produced by the reaction of phosphates with molybdates and are used in testing for the presence of phosphates.ΚΠ 1866 Proc. Royal Soc. 15 78 It gives a precipitate..with phosphomolybdic acid, bichloride of platinum, and terchloride of gold. 1924 J. B. Cohen Pract. Org. Chem. (ed. 3) 463 A solution of phosphomolybdic acid in nitric acid..gives yellow precipitates of different shades [with alkaloids]. 1987 C. M. F. Simpson et al. in A. J. Turner & H. S. Bachelard Neurochemistry vii. 206 This assay..involves the oxidation of phospholipid by perchloric acid with the release of inorganic phosphate which reacts with ammonium molybdate to form phosphomolybdic acid. phosphoprotein n. Brit. /ˌfɒsfə(ʊ)ˈprəʊtiːn/ , U.S. /ˌfɑsfoʊˈproʊˌtin/ Biochemistry any protein containing phosphate groups.ΚΠ 1908 Jrnl. Biol. Chem. 4 p. l Joint Recommendations of the Physiological and Biochemical Committees on Protein Nomenclature... Phosphoproteins. Compounds of the protein molecule with some, as yet undefined, phosphorus containing substance other than a nucleic acid or lecithin. 1929 R. A. Gortner Outl. Biochem. xvi. 391 Casein of milk and vitellin of egg yolk are the two most important phosphoproteins. 1992 S. Rose Making of Memory 41 The ATP in its turn was used to synthesize a special class of phosphorus-containing proteins, phosphoproteins, present in very large amounts in the brain. phosphosilicate n. Brit. /ˌfɒsfə(ʊ)ˈsɪlᵻkᵻt/ , /ˌfɒsfə(ʊ)ˈsɪlᵻkeɪt/ , U.S. /ˌfɑsfoʊˈsɪləˌkeɪt/ , /ˌfɑsfoʊˈsɪləkət/ a substance, esp. a glass, which consists largely of phosphorus and silicon oxides, or is both a phosphate and a silicate; frequently attributive.ΘΚΠ the world > matter > chemistry > elements and compounds > metals > specific elements > phosphorus > [noun] > compounds > other phosphonium1859 phosphine1870 phosphonitrile1921 phosphorane1952 tepa1953 phosphosilicate1964 1964 IBM Jrnl. Res. & Devel. 8 378/2 The importance of the phosphosilicate layer for transistor stabilization has also been shown by the examination of production transistors after life tests. 1975 Physics Bull. Jan. 14/1 A team at Southampton University has also achieved very low losses with a new type of fibre—a phosphosilicate (P2O5/SiO2) glass core contained in a pure silica cladding. 1997 Proc. National Acad. Sci. U.S.A. 94 9114/2 Briefly, phosphosilicate glass..is placed on a silicon wafer. phosphotungstate n. Brit. /ˌfɒsfə(ʊ)ˈtʌŋsteɪt/ , /ˌfɒsfə(ʊ)ˈtʌŋstət/ , U.S. /ˌfɑsfoʊˈtəŋˌsteɪt/ Chemistry a salt of phosphotungstic acid; an anion containing phosphorus together with several tungsten and oxygen atoms, esp. PW12O403−.ΚΠ 1865 E. Parrish Treat. Pharmacy (ed. 3) 626 Another very important test for the discovery of the alkaloids is Scheibler's phospho-tungstate of soda, a solution containing only 1/ 200000 part of strychnia is rendered opalescent. 1938 M. S. Dunn in C. L. A. Schmidt Chem. Amino Acids & Proteins ii. 79 Lysine is purified as the phosphotungstate and isolated as the dipicrate and dihydrochloride. 1982 T. M. Devlin Textbk. Biochem. vi. 272 (caption) The enzyme complex was negatively stained with phosphotungstate. phosphotungstic adj. Brit. /ˌfɒsfə(ʊ)ˈtʌŋstɪk/ , U.S. /ˌfɑsfoʊˈtəŋstɪk/ Chemistry phosphotungstic acid, a complex acid, H3PW12O40, produced by the reaction of phosphates with tungstates and used as a precipitant for proteins, alkaloids, and purines.ΚΠ 1879 Jrnl. Amer. Chem. Soc. 1 111 The author [sc. W. Gibbs] modifies a former statement concerning salts of phosphotungstic acid containing more than 6 atoms of base, the supposed 7th and 8th atom salts proving to be either mixtures or salts of other series. 1934 C. C. Steele Introd. Plant Biochem. v. xiii. 132 The most widely used method is precipitation from solution with phosphotungstic acid. 1995 McGill Jrnl. Med. Spring 16/2 Incubations were carried out for 15 min at 37°C and stopped by the addition of 1.0 ml of ice-cold 1% phosphotungstic acid. ΚΠ 1838 T. Thomson Chem. Org. Bodies 186 Phosphovinate of barytes was the salt which M. Pelouze chiefly studied, and by means of which, he determined the composition of phosphovinic acid. 1866 H. Draper Text-bk. Chem. 414 Phosphovinic Acid (C4H5O,PO5+2HO)..is a syrupy liquid, of a sour taste, and dissolves in water, alcohol, and ether readily. phosphowolframic adj. Brit. /ˌfɒsfə(ʊ)wʊlˈframɪk/ , /ˌfɒsfə(ʊ)vɒlˈframɪk/ , U.S. /ˌfɑsfoʊˌwʊlˈfræmɪk/ Chemistry (now rare) phosphowolframic acid = phosphotungstic acidΚΠ 1878 C. T. Kingzett Animal Chem. 276 By precipitation of its hydrochloric acid solution with phosphowolframic acid. 1904 Lancet 5 Mar. 654 Secondly, there was found a marked decrease in the proportion of uric acid nitrogen and other bodies precipitated by phospho-wolframic acid. 1980 Jrnl. Nat. Products 43 196 The filtrate was acidified with sulfuric acid, and the alkaloids were precipitated with phosphowolframic acid. This entry has been updated (OED Third Edition, March 2006; most recently modified version published online March 2022). < comb. form1838 |
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