单词 | phosphoenolpyruvate |
释义 | phosphoenolpyruvaten. Biochemistry. The anion CH2=C(OPO(OH)2)COO−, or a compound containing this, the conversion of which to pyruvate in glycolysis provides a phosphate group for the formation of ATP from ADP. Abbreviated PEP. ΘΚΠ the world > matter > chemistry > organic chemistry > salts, esters or anions of organic acids > [noun] hydrochloride1823 isethionates1838 citraconate1840 adipate1841 anthranilate1841 stearate1841 itaconic acid1842 salicylate1842 oenanthate1845 ammelide1846 pelargonate1848 pelargyl1851 melanuric acid1852 methylate1852 opianyl1852 abietate1853 maleate1853 fulminuric1856 glyoxylate1856 urethane1856 indican1859 oxalyl1859 malonate1862 methacrylate1865 amylate1866 acetoacetate1873 isobutyrate1873 glutamate1876 hydrobromide1877 nicotinate1879 isovalerate1882 calcium gluconate1884 methoxide1885 isophthalate1886 homogentisate1891 naphthenate1899 peracetate1901 iodoacetate1902 glucuronate1904 hydnocarpate1905 thiomalate1905 azide1907 phytate1908 linolenate1909 isocitrate1925 phenylpyruvate1926 monosodium glutamate1929 perester1933 phosphonate1934 polymethacrylate1935 pantothenate1938 phosphoenolpyruvate1941 nylon salt1945 pantoate1945 penicilloate1946 thymidylate1959 chorismate1965 nonanoate1965 neuraminate1970 1939 A. T. Shohl Mineral Metabolism vii. 180 (note) The formation of two new phosphoric esters, (+)-2-phosphoglyceric acid and phospho-enol-pyruvic acid.] 1941 Science 18 July 68/1 The energy-rich phosphate bonds are of the type..represented by such compounds as..phosphoenol-pyruvate. 1956 W. F. H. M. Mommaerts in O. H. Gaebler Enzymes xiv. 319 The system consists..of a hydrolyzing enzyme (actomyosin), a common substrate (ATP), a resynthesizing enzyme (pyruvate kinase), and a reservoir substrate (phosphoenol pyruvate or PEP). 1970 New Scientist 23 Apr. 168/1 The last step in the glycolytic pathway, from phosphoenolpyruvate to pyruvate, is effectively irreversible. 1985 Cambr. Encycl. Life Sci. i. 25/2 Carbon dioxide is first fixed in mesophyll cells near the leaf surface by phospho-enol-pyruvate carboxylase, an enzyme with a high affinity for carbon dioxide. 1992 M. Ingrouille Diversity & Evol. Land Plants 226 Atmospheric carbon dioxide is taken up by an acceptor molecule phosphoenolpyruvate (PEP) to produce malate which is stored in the large vacuoles of succulent tissue cells. This entry has been updated (OED Third Edition, March 2006; most recently modified version published online March 2022). < n.1941 |
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