单词 | picoline |
释义 | picolinen. Chemistry. Each of three colourless, pungent-smelling, liquid bases, (CH3)C5H4N, that are isomeric methyl derivatives of pyridine and are obtained from coal tar, bone oil, etc.; spec. the α-isomer (2-methylpyridine). ΘΚΠ the world > matter > chemistry > organic chemistry > chemicals from tar > [noun] naphthalene1821 idryl1845 picoline1846 fluorene1867 fluoranthene1878 isoquinoline1886 indene1888 1846 T. Anderson in Edinb. New Philos. Jrnl. 41 149 The attempt to separate this pyrrol proved that it was present in extremely minute quantity only, but led to the discovery of a new base different from those of Runge, for which I propose the name of Picoline. 1865 C. B. Mansfield Theory of Salts 263 The double series of isomeric compounds, of which Aniline and Picoline are respectively members. 1875 A. B. Prescott Outl. Proximate Org. Anal. 132 Ammonia, anilin, nicotia, picolin, as sulphates, are not soluble in ether. 1946 A. A. Morton Chem. Heterocyclic Compounds viii. 213 Picolinic acid..is obtained in 50 to 51 percent yield from α-picolin. 1955 Sci. Amer. July 66/1 Some of the products already evolving are new types of phenolic plastics, new pharmaceuticals based on quinoline (nicotinic acid) and on picoline (tuberculosis drugs), and new rocket fuels. 1993 Nature 9 Dec. 514/2 In 1989 Jordan and Taylor discovered a cationic zirconium complex that could catalyse the insertion of ethylene, propene or 1-butene into the ortho CH bond of picoline. This entry has been updated (OED Third Edition, March 2006; most recently modified version published online March 2022). < n.1846 |
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