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单词 photoisomerize
释义

photoisomerizev.

Brit. /ˌfəʊtəʊˈʌɪsəmərʌɪz/, U.S. /ˌfoʊdoʊˈaɪsəməˌraɪz/
Forms: 1900s– photoisomerise, 1900s– photoisomerize.
Origin: Formed within English, by compounding. Etymons: photo- comb. form, isomerize v.
Etymology: < photo- comb. form + isomerize v., after photoisomerization n.
Chemistry.
intransitive. To undergo photoisomerization. Also transitive: to cause to undergo photoisomerization.
ΘΚΠ
the world > matter > chemistry > isomerism > undergo isomerism [verb (intransitive)] > undergo photoisomerization
photoisomerize1960
1960 Jrnl. Amer. Chem. Soc. 82 2023/1 Under similar conditions the unchlorinated diacid of the same structure has been shown to photoisomerize to quadricyclo[2,2,1,0,2,603,5]heptane-2,3-dicarboxylic acid.
1984 N. N. Greenwood & A. Earnshaw Chem. of Elements (1986) vi. 202 Oxidation of claro-B10H102− with aqueous solutions of Fe iii or Ce iv (or electrochemically) yields conjuncto-B20H182− which can be photoisomerized to neo-B20H182−.
2001 Science (Nexis) 21 Sept. 2171 Irradiation at 365 nanometers then photoisomerizes the E to the Z isomer, which dethreads.
This entry has been updated (OED Third Edition, March 2006; most recently modified version published online March 2022).
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v.1960
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