propargylicadj.

Brit.

/ˌprəʊpɑːˈdʒɪlɪk/, U.S.

/ˌproʊpɑrˈdʒɪlɪk/

Origin: A borrowing from German, combined with an English element. Etymons: German Propargyl , -ic suffix.

Etymology: < German Propargyl propargyl n. (the English word is first attested slightly later) + -ic suffix.In propargylic ether n. at Compounds after German Propargyläther (C. Liebermann 1864, in Zeitschr. f. Chem. u. Pharm. 749).

Chemistry.

Of or containing propargyl.Recorded earliest in propargylic ether n. at Compounds.

ΚΠ

1866 H. Watts Dict. Chem. IV. 728 Propargylic ether.—When tribromide of allyl is digested..with alcoholic potash, the alcohol distilled therefrom yields with ammoniacal silver-nitrate a white precipitate..regarded by Liebermann as the silver-salt of an ether to which he gives the name above.

1876 H. E. Armstrong Introd. to Study of Org. Chem. vi. 163 Propargylic alcohol is a colourless mobile liquid.

1938 Jrnl. Amer. Chem. Soc. 60 1714/1 Propargylic acetal, obtained from acrolein.

1988 Philos. Trans. (Royal Soc.) A. 326 651 Methods of generating the cobalt-complexed propargylic cation using trifluoroacetic acid.

Compounds

propargylic acid n. = propiolic acid n. at propiolic adj.

ΚΠ

1940 Chambers's Techn. Dict. 678/1 Propargylic acid.

1962 New Scientist 9 Aug. 302/3 Coumarin and propargylic acid are well known for their ability to increase brightness.

1998 Tetrahedron 54 5763 2-carboxyvinyltriphenylphosphonium bromide..was synthesized starting from propargylic acid.

propargylic ether n. an ether containing a propargyl group; (originally) †ethyl propargyl ether, CH≡CCH₂OCH₂CH₃ (obsolete).

ΚΠ

1866propargylic ether [see main sense].

1872 H. Watts Dict. Chem. VI. 958 Propargylic ether..is a liquid having an offensive odour, boiling at 72°.

1966 Jrnl. Org. Chem. 31 2885/2 Phenyl-substituted propargylic ethers and thio ethers have been easily isomerized to the allenes with potassium tertiary butoxide in dimethyl sulfoxide.

2002 Jrnl. Organometallic Chem. 653 209 It is known that the propargylic ether can react with an organocopper reagent.

This entry has been updated (OED Third Edition, June 2007; most recently modified version published online March 2022).

单词	propargylic
释义	propargylicadj. Brit. /ˌprəʊpɑːˈdʒɪlɪk/, U.S. /ˌproʊpɑrˈdʒɪlɪk/ Origin: A borrowing from German, combined with an English element. Etymons: German Propargyl , -ic suffix. Etymology: < German Propargyl propargyl n. (the English word is first attested slightly later) + -ic suffix.In propargylic ether n. at Compounds after German Propargyläther (C. Liebermann 1864, in Zeitschr. f. Chem. u. Pharm. 749). Chemistry. Of or containing propargyl.Recorded earliest in propargylic ether n. at Compounds. ΚΠ 1866 H. Watts Dict. Chem. IV. 728 Propargylic ether.—When tribromide of allyl is digested..with alcoholic potash, the alcohol distilled therefrom yields with ammoniacal silver-nitrate a white precipitate..regarded by Liebermann as the silver-salt of an ether to which he gives the name above. 1876 H. E. Armstrong Introd. to Study of Org. Chem. vi. 163 Propargylic alcohol is a colourless mobile liquid. 1938 Jrnl. Amer. Chem. Soc. 60 1714/1 Propargylic acetal, obtained from acrolein. 1988 Philos. Trans. (Royal Soc.) A. 326 651 Methods of generating the cobalt-complexed propargylic cation using trifluoroacetic acid. Compounds propargylic acid n. = propiolic acid n. at propiolic adj. ΚΠ 1940 Chambers's Techn. Dict. 678/1 Propargylic acid. 1962 New Scientist 9 Aug. 302/3 Coumarin and propargylic acid are well known for their ability to increase brightness. 1998 Tetrahedron 54 5763 2-carboxyvinyltriphenylphosphonium bromide..was synthesized starting from propargylic acid. propargylic ether n. an ether containing a propargyl group; (originally) †ethyl propargyl ether, CH≡CCH₂OCH₂CH₃ (obsolete). ΚΠ 1866propargylic ether [see main sense]. 1872 H. Watts Dict. Chem. VI. 958 Propargylic ether..is a liquid having an offensive odour, boiling at 72°. 1966 Jrnl. Org. Chem. 31 2885/2 Phenyl-substituted propargylic ethers and thio ethers have been easily isomerized to the allenes with potassium tertiary butoxide in dimethyl sulfoxide. 2002 Jrnl. Organometallic Chem. 653 209 It is known that the propargylic ether can react with an organocopper reagent. This entry has been updated (OED Third Edition, June 2007; most recently modified version published online March 2022). < adj.1866
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