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单词 purpurogallin
释义

purpurogallinn.

Brit. /ˌpəːpjᵿrə(ʊ)ˈɡalɪn/, U.S. /ˈˌpərp(j)əroʊˈɡæl(ə)n/
Origin: A borrowing from French. Etymon: French purpurogalline.
Etymology: < French purpurogalline (A. Girard 1869, in Comptes rendus hebd. de l'Acad. des Sci. 69 866) < purpur- (in purpurine purpurin n.) + -ogall- (in pyrogallique pyrogallic adj.; compare quot. 1872) + -ine -in suffix1. The dye was so named after the unrelated purpurin (see purpurin n. 2) by analogy with the preparation of that substance by oxidation of alizarin.
Chemistry.
An orange-red crystalline dye, originally prepared by mild oxidation of pyrogallol and later found to occur in some oak galls.Purpurogallin is a tetrahydric phenol with fused tropolone and trihydroxybenzene rings; C11H8O5.
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the world > matter > chemistry > organic chemistry > hydrocarbons > [noun] > benzene derivatives > phenols > others
phenetidine1851
nitrophenol1852
carvacrol1854
guaiacol1864
hydroquinone1865
iodophenol1868
pentachlorophenol1869
trichlorophenol1871
purpurogallin1872
xylenol1872
kosin1875
phloroglucinol1879
cerulignol1883
cannabinol1896
gossypol1899
thiophenol1899
phenol resin1911
oxine1927
nordihydroguaiaretic acid1944
1872 Jrnl. Chem. Soc. 25 703 Purpurogallin, the substance obtained by Girard..from pyrogallic acid by the action of silver nitrate,..is the principal product of the oxidation effected by lead peroxide, hydrogen peroxide, [etc.].
1919 Jrnl. Chem. Soc. 115 1329 The investigation of the red colouring matter derived from the ‘red pea gall’ has..to some extent proved disappointing. It was found that dryophantin..was in no way allied either to the flavones or to the anthocyanins, but..consisted of purpurogallin and two molecules of dextrose.
1968 Kirk-Othmer Encycl. Chem. Technol. (ed. 2) XVI. 191 Purpurogallin..a red-brown to black mordant dye, results from electrolytic and other mild oxidations of pyrogallol.
1994 New Phytologist 128 166/2 The concentration of purpurogallin formed was determined spectrophotometrically.
This entry has been updated (OED Third Edition, December 2007; most recently modified version published online March 2022).
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n.1872
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