pyromucicadj.

Brit.

/ˌpʌɪrəʊˈmjuːsɪk/, U.S.

/ˌpaɪroʊˈmjusɪk/

Origin: Formed within English, by derivation; modelled on a French lexical item. Etymons: pyromucous adj., -ic suffix, pyro- comb. form, mucic adj.

Etymology: In sense 1 < pyromuc- (in pyromucous adj. + -ic suffix), after French pyromucique, designating radicals corresponding to pyromucous acid ( L.-B. Guyton de Morveau et al. Méthode de nomencl. chim. (1787) 81). In sense 2 < pyro- comb. form + mucic adj., after French acide pyro-mucique (J. J. de Houtou-Labillardière 1818, in Ann. de chim. et de physique 9 366).

Chemistry. Now rare.

1. Originally: †relating to pyromucous acid obsolete (see pyromucous adj.). In later use: relating to or derived from pyromucic acid.

ΚΠ

1788 J. St. John tr. L. B. Guyton de Morveau et al. Method Chym. Nomencl. 38 Pyro-mucic radical [Fr. radical pyro-mucique].

1877 H. Watts Dict. Chem. IV. 765 Pyromucic alcohol.

1879 H. Watts Dict. Chem. (ed. 2) VIII. i. 832 Furfural or furfurol, C₅H₄O₂. Pyromucic aldehyde.

2000 V. O. Sheftel Indirect Food Additives & Polymers i. 96 2-Furaldehyde..Synonyms:..Pyromucic aldehyde.

2. pyromucic acid n. a crystalline acid produced by the destructive distillation of mucic acid.Systematic name: furan-2-carboxylic acid, (C₄H₃O)COOH.

ΚΠ

1819 tr. H. Labillardiere in Ann. Philos. 14 267 This acid, which I shall distinguish hereafter by the name of pyromucic, is white, destitute of smell, of a strong acid taste, [etc.].

1836–41 W. T. Brande Man. Chem. (ed. 5) 1072 When mucic acid is subjected to destructive distillation it yields..pyromucic acid.

1962 M. P. Crosland Hist. Stud. Lang. Chem. v. i. 292 By heating gallic acid, citric acid or mucic acid etc. under suitable conditions, chemists obtained new acids which they called ‘pyrogallic acid’, ‘pyrocitric acid’ and ‘pyromucic acid’.

1989 Merck Index (ed. 11) 674/1 2-Furoic acid... Pyromucic acid.

Derivatives

pyroˈmucamide n. [after French pyromucamide (F. Malaguti 1846, in Comptes rendus hebd. de l'Acad. des Sci. 22 856)] rare an amide derived from pyromucic acid.Systematic name: furan-2-carboxamide, (C₄H₃O)CONH₂.

ΚΠ

1847 Chem. Gaz. 5 85 Pyromucamide differs essentially from this body.

1952 Industr. & Engin. Chem. 44 1009/1 In particular, furfuraldoxime was transformed into pyromucamide in 80% yield by heating for 1 hour at 100° with about half its weight of catalyst.

pyroˈmucyl n. the acyl radical —OC·(C₄H₃O), derived from pyromucic acid.

ΚΠ

1866 H. Watts Dict. Chem. IV. 763 With pentachloride of phosphorus it [sc. pyromucic acid] yields chloride of pyromucyl, C⁵H³O²Cl.

1923 Jrnl. Amer. Chem. Soc. 45 520 A new sample (1 g.) of pyromucyl-hydroxamic acid was dissolved in ethyl acetate as before.

1948 Obituary Notices Fellows Royal Soc. 5 709 The introduction of a cyclic group such as benzoyl, toluyl, pyromucyl, or phenacetyl in near proximity to an asymmetric carbon atom.

This entry has been updated (OED Third Edition, December 2007; most recently modified version published online March 2022).

单词	pyromucic
释义	pyromucicadj. Brit. /ˌpʌɪrəʊˈmjuːsɪk/, U.S. /ˌpaɪroʊˈmjusɪk/ Origin: Formed within English, by derivation; modelled on a French lexical item. Etymons: pyromucous adj., -ic suffix, pyro- comb. form, mucic adj. Etymology: In sense 1 < pyromuc- (in pyromucous adj. + -ic suffix), after French pyromucique, designating radicals corresponding to pyromucous acid ( L.-B. Guyton de Morveau et al. Méthode de nomencl. chim. (1787) 81). In sense 2 < pyro- comb. form + mucic adj., after French acide pyro-mucique (J. J. de Houtou-Labillardière 1818, in Ann. de chim. et de physique 9 366). Chemistry. Now rare. 1. Originally: †relating to pyromucous acid obsolete (see pyromucous adj.). In later use: relating to or derived from pyromucic acid. ΚΠ 1788 J. St. John tr. L. B. Guyton de Morveau et al. Method Chym. Nomencl. 38 Pyro-mucic radical [Fr. radical pyro-mucique]. 1877 H. Watts Dict. Chem. IV. 765 Pyromucic alcohol. 1879 H. Watts Dict. Chem. (ed. 2) VIII. i. 832 Furfural or furfurol, C₅H₄O₂. Pyromucic aldehyde. 2000 V. O. Sheftel Indirect Food Additives & Polymers i. 96 2-Furaldehyde..Synonyms:..Pyromucic aldehyde. 2. pyromucic acid n. a crystalline acid produced by the destructive distillation of mucic acid.Systematic name: furan-2-carboxylic acid, (C₄H₃O)COOH. ΚΠ 1819 tr. H. Labillardiere in Ann. Philos. 14 267 This acid, which I shall distinguish hereafter by the name of pyromucic, is white, destitute of smell, of a strong acid taste, [etc.]. 1836–41 W. T. Brande Man. Chem. (ed. 5) 1072 When mucic acid is subjected to destructive distillation it yields..pyromucic acid. 1962 M. P. Crosland Hist. Stud. Lang. Chem. v. i. 292 By heating gallic acid, citric acid or mucic acid etc. under suitable conditions, chemists obtained new acids which they called ‘pyrogallic acid’, ‘pyrocitric acid’ and ‘pyromucic acid’. 1989 Merck Index (ed. 11) 674/1 2-Furoic acid... Pyromucic acid. Derivatives pyroˈmucamide n. [after French pyromucamide (F. Malaguti 1846, in Comptes rendus hebd. de l'Acad. des Sci. 22 856)] rare an amide derived from pyromucic acid.Systematic name: furan-2-carboxamide, (C₄H₃O)CONH₂. ΚΠ 1847 Chem. Gaz. 5 85 Pyromucamide differs essentially from this body. 1952 Industr. & Engin. Chem. 44 1009/1 In particular, furfuraldoxime was transformed into pyromucamide in 80% yield by heating for 1 hour at 100° with about half its weight of catalyst. pyroˈmucyl n. the acyl radical —OC·(C₄H₃O), derived from pyromucic acid. ΚΠ 1866 H. Watts Dict. Chem. IV. 763 With pentachloride of phosphorus it [sc. pyromucic acid] yields chloride of pyromucyl, C⁵H³O²Cl. 1923 Jrnl. Amer. Chem. Soc. 45 520 A new sample (1 g.) of pyromucyl-hydroxamic acid was dissolved in ethyl acetate as before. 1948 Obituary Notices Fellows Royal Soc. 5 709 The introduction of a cyclic group such as benzoyl, toluyl, pyromucyl, or phenacetyl in near proximity to an asymmetric carbon atom. This entry has been updated (OED Third Edition, December 2007; most recently modified version published online March 2022). < adj.1788
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