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单词 stereocontrol
释义

> as lemmas

stereocontrol
stereocontrol n.
Brit. /ˌstɛrɪəʊkənˈtrəʊl/
,
/ˌstɪərɪəʊkənˈtrəʊl/
,
U.S. /ˌstɛrioʊkənˈtroʊl/
,
/ˌstɪrioʊkənˈtroʊl/
Chemistry the control of a synthesis by the choice of reagents and reaction conditions so as to produce a product with a desired stereochemical conformation; also as v. transitive, to control thus.
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the world > matter > chemistry > chemical structure or stereochemistry > form according to chemical structure [verb (transitive)] > specific through stereocontrol
stereocontrol1959
the world > matter > chemistry > chemical structure or stereochemistry > [noun] > conformation > stereocontrol
stereocontrol1959
1959 Gaylord & Mark Linear & Stereoregular Addition Polymers 478 The propagation reaction will be stereoregulated or stereocontrolled and the polymer will be tactic, which means that the individual monomers in the chain will overwhelmingly be added in one of the different possible ways and the resulting macromolecule will display stereospecificity, i.e., a high degree of internal orderliness.
1970 Jrnl. Macromol. Sci.: Chem. A. 4 1014 A very useful technique for the exploration of the stereocontrol of ionic polymerizations.
1979 Tetrahedron Lett. No. 40. 3805 Unique stereocontrol in aldolization at C6 of penicillanates through modification of solvent and cation has been observed.
extracted from stereo-comb. form
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