单词 | tachysterol |
释义 | tachysteroln. Biochemistry. An oily isomer of ergosterol and lumisterol, C28H43OH, which will form calciferol when irradiated with ultraviolet light. ΘΚΠ the world > matter > chemistry > organic chemistry > alcohols > [noun] > steroid alcohols > sterols > named cinchol1885 cholesterol1894 phytosterol1898 sitosterol1898 stigmasterol1907 lanosterol1929 suprasterol1930 lumisterol1932 tachysterol1933 1933 Chem. Abstr. 27 729 The addn. compd. from irradiated ergosterol and citraconic anhydride (20 g.) and 75 cc. Ac2O, warmed 2 hrs., give [sic] 7 g. of tachysteryl acetate citraconic anhydride... Tachysterol..has not been crystd. 1954 A. White et al. Princ. Biochem. l. 1053 Of the series of compounds obtained from the irradiation of ergosterol only calciferol (vitamin D2) possesses antirachitic activity. However, one of the series, tachysterol, may be catalytically reduced to dihydrotachysterol.., which is antirachitic. 1976 H. Campion et al. in B. E. C. Nordin Calcium, Phosphate & Magnesium Metabolism xii. 445 Lythgoe has reported the synthesis of a closely related isomer, tachysterol, by a nonphotochemical pathway. This entry has not yet been fully updated (first published 1986; most recently modified version published online June 2018). < n.1933 |
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