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单词 tautomerize
释义

tautomerizev.

Brit. /tɔːˈtɒmərʌɪz/, U.S. /ˌtɔˈtɑməˌraɪz/, /ˌtɑˈtɑməˌraɪz/
Forms: 1900s– tautomerise, 1900s– tautomerize.
Origin: Formed within English, by derivation; modelled on a German lexical item. Etymons: tautomer n., -ize suffix.
Etymology: < tautomer n. + -ize suffix, after German tautomerisieren (1899 or earlier). Compare earlier tautomerizable adj., tautomerization n.
Chemistry.
intransitive. To undergo conversion into another tautomeric form. Also transitive: to convert (a compound) into a tautomeric form.
ΘΚΠ
the world > matter > chemistry > isomerism > undergo isomerism [verb (intransitive)] > undergo tautomerization
tautomerize1905
1905 Proc. Chem. Soc. 21 165 It is also possible that the very energetic ultra-violet light used by Mr. Baly exerts some action on the solutions of substances capable of being tautomerised.
1911 Jrnl. Amer. Chem. Soc. 33 1213 The normal carbinol halides, even in the absence of excess of acid, tautomerize spontaneously to the colored quinoid state.
1957 R. H. Thomson Naturally Occurring Quinones ii. 20 It is not possible, as a rule, to tautomerize a benzoquinol to the diketo form.
1972 R. A. Jackson Mechanism iv. 60 This could plausibly lose carbon dioxide to give the carbanion 82 which would rapidly tautomerize to pyridine 83 by a proton shift.
2006 J. M. Hornback Org. Chem. (Internat. Student ed.) xi. 430 The enol cannot be isolated because it spontaneously tautomerizes to a ketone.
This entry has been updated (OED Third Edition, June 2014; most recently modified version published online March 2022).
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