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单词 butadiene
释义

butadienen.

Brit. /ˌbjuːtəˈdʌɪiːn/, U.S. /ˌbjudəˈdaɪˌin/
Origin: Formed within English, by compounding. Etymons: butane n., di- comb. form, -ene comb. form.
Etymology: < buta- (in butane n.) + di- comb. form + -ene comb. form.
Chemistry.
Either of two isomeric hydrocarbons of the alkene series, gaseous at room temperature, with general formula C4H6; esp. 1,3-butadiene, used as a monomer in the production of synthetic rubbers; (also) any substituted derivative of these alkenes.1,3-butadiene is CH2=CHCH=CH2; 1,2-butadiene is CH2=C=CHCH3. The presence of two adjacent double bonds in 1,2-butadiene makes it very unstable, and of little use synthetically.
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the world > matter > chemistry > organic chemistry > hydrocarbons > [noun] > dienes
conylene1863
butadiene1893
alkadiene1915
1893 Chem. News 21 Apr. 193/2 The author has set out from a non-saturated carbide, divinyl or butadiene, and has obtained an (optically) inactive erythrite incapable of being split up.
1911 Chem. Abstr. 5 3519 Hydrocarbons of the Butadiene Series and Artificial Caoutchoucs.
1937 Discovery Aug. 247/1 The real raw material of synthetic rubber—a product known as butadiene.
1977 J. March Adv. Org. Chem. (ed. 2) x. 408 Vinyl halides can be coupled to give 1,3-butadienes by treatment with activated copper powder.
2016 Jrnl. Physical Chem. C. 120 23566/1 A representative example of such an industrially important process is a sustainable synthesis of butadiene from ethanol.

Compounds

attributive and in the names of polymers derived from butadiene, as butadiene-acrylonitrile, butadiene-styrene.
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1906 Jrnl. Chem. Soc.: Trans. 89 225 A still more striking instance has been brought to light quite recently by Stobbe.., in working with certain carboxylic acids of the butadiene series.
1943 H. M. Langton in R. S. Morrell Synthetic Resins (ed. 2) i. 40 Buna 85 is a pure butadiene polymer, Buna S a mixed polymer of butadiene and styrene.
1959 Times 13 Mar. 10/1 (advt.) Cariflex general purpose butadiene-styrene rubber.
1959 Times 27 Apr. (Suppl.) p. vi/7 For oil and fuel resistance the butadiene-acrylonitrile type rubbers are in common use.
2015 Chem. Materials 27 4809/1 There exists a reasonably strong interaction between the platinum centers and the butadiene alkenes.
This entry has been updated (OED Third Edition, September 2018; most recently modified version published online December 2021).
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n.1893
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