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单词 zirconyl
释义

zirconyln.

Brit. /ˈzəːkənʌɪl/, /ˈzəːkənɪl/, U.S. /ˈzərkəˌnɪl/
Origin: A borrowing from German. Etymon: German Zirkonyl.
Etymology: < German Zirkonyl (R. Hornberger 1876, in Ann. d. Chem. 81 238) < Zirkon- (in Zirkonium zirconium n.) + -yl -yl suffix.
Chemistry.
A cationic group containing zirconium and oxygen present in some salts and aqueous solutions. Usually as a modifier forming chemical names, as in zirconyl chloride.Commonly written ZrO2+ but better represented by a more complex formula such as [Zr4(OH)8]8+.
ΚΠ
1887 Jrnl. Chem. Soc. 52 ii. 778 Zirconyl chloride, ZrOCl2 + 8H2O, is obtained crystallised in prismatic needles from a hydrochloric acid solution of the so-called zirconium oxychloride.
1946 Nature 24 Aug. 275/2 It [sc. an analytical method] is based on the bleaching of the lake from a zirconyl salt and sodium alizarin sulphonate by the fluoride ion.
1954 Thorpe's Dict. Appl. Chem. (ed. 4) XI. 1119/1 Zirconyl citrate..may be prepared by adding a dilute solution of citric acid to a freshly prepared solution of zirconyl chloride.
2008 Appl. Catalysis B. 85 87/2 Ammonium metatungstate, zirconyl chloride octahydrate, aluminum nitrate and tetraethoxysilane were obtained from Sigma-Aldrich, MO, USA.
This entry has been updated (OED Third Edition, March 2021; most recently modified version published online March 2022).
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