having the properties of or pertaining to a diastereoisomer
Examples of 'diastereomeric' in a sentence
diastereomeric
Yields ranging from moderate to good and diastereomeric ratios up to 95:5 are achieved.
Renato Noto, Paolo Lo Meo, Michelangelo Gruttadauria, Carmela Aprile, Serena Riela 2005, 'Diastereoselective Synthesis of 2-Phenylselenenyl-1,3-anti-Diols and 2-Phenylselenenyl-1,3-anti-Azido-Alcoholsvia Hydroxyand Azido-Selenenylation Reactions', Moleculeshttp://www.mdpi.com/1420-3049/10/2/383/. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Unambiguous stereochemical assignments of both diastereomeric series are reported.
Faiz Ahmed Khan, Karuppasamy Parasuraman 2010, 'Synthesis of oxa-bridged derivatives from Diels–Alder bis-adducts of butadiene and1,2,3,4-tetrahalo-5,5-dimethoxycyclopentadiene', Beilstein Journal of Organic Chemistryhttps://doi.org/10.3762/bjoc.6.64. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
By further cultivation and analysis, we could isolate 1a and 1b in different diastereomeric ratio.
Mårten Strand, Marcus Carlsson, Hanna Uvell, Koushikul Islam, Karin Edlund, IngerCullman, Björn Altermark, Ya-Fang Mei, Mikael Elofsson, Nils-Peder Willassen, GöranWadell, Fredrik Almqvist 2014, 'Isolation and Characterization of Anti-Adenoviral Secondary Metabolites from MarineActinobacteria', Marine Drugshttp://www.mdpi.com/1660-3397/12/2/799. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The article describes a two-step synthesis of diastereomeric 3-hydroxy-2-methyl-3-(4-biphenylyl)butanoic acids.
Ivan O. Juranic, Sote M. Vladimirov, Bojan D. Markovic, Zorica D. Juranic, Silva Lj.Dobric, Sanda P. Dilber 2008, 'Docking Studies and Anti-inflammatory Activity of β-Hydroxy-β-arylpropanoicAcids', Moleculeshttp://www.mdpi.com/1420-3049/13/3/603/. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Purification of enantiomeric mixtures was examined, and recrystallization of the diastereomeric salt was found to be the most efficient solution.
Miklós Hunor Bosits, Emese Pálovics, János Madarász, Elemér Fogassy 2019, 'New Discoveries in Enantiomeric Separation of Racemic Tofisopam', Journal of Chemistryhttp://dx.doi.org/10.1155/2019/4980792. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The racemic mixture was resolved by diastereomeric salt formation using 1-phenylethylamine enantiomers as resolving agents.
Claudio Bruno, Giovanni Lentini, Angelo Lovece, Maria Maddalena Cavalluzzi, AlessiaCarocci, Alessia Catalano, Carlo Franchini 2013, 'Microwave-Assisted Synthesis of (±)-Mandelic Acid-d5, Optical Resolution, and AbsoluteConfiguration Determination', Journal of Chemistryhttp://dx.doi.org/10.1155/2013/386238. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The first acid-catalyzed intramolecular transacetalization gave a mixture of diastereomeric2-benzofurans 18 (ratio of diastereomers 2:2:1:1).
Samuel Asare-Nkansah, Bernhard Wünsch 2016, 'Double Intramolecular Transacetalization of Polyhydroxy Acetals: Synthesis of Conformationally-Restricted1,3-Dioxanes with Axially-Oriented Phenyl Moiety', Moleculeshttp://www.mdpi.com/1420-3049/21/11/1503. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The single crystals for the pair of diastereomeric salts were cultivated and their crystal structureswere examined thoroughly.
Yangfeng Peng, Cai Feng, Sohrab Rohani, Quan He 2018, 'Improved Resolution of 4-Chloromandelic Acid and the Effect of Chlorine InteractionsUsing (R)-(+)-Benzyl-1-Phenylethylamine as a Resolving Agent', Moleculeshttps://www.mdpi.com/1420-3049/23/12/3354. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)