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单词 ethynyl
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ethynyl

In this study, 1,8-naphthalimide derivatives containing ethynyl link were synthesized and characterized.We have synthesized a family of compounds featuring ferrocenediyl-ethynyl units withvarious para-substituted aromatic linkages.The reactions have been found to be sensitive to the substitution of the ethynyl group.These compounds are interesting variations on the pinnatifidenyne structure that included the first examples of ethynyl oxiranederivatives (3–4).Ethynyl[2.2]paracyclophanes are shown to be useful substrates for the preparation of complex, highly unsaturated carbon frameworks.Cell proliferation and viability was detected by cell counting kit-8 and 5-ethynyl-2′-deoxyuridine assay.Pulse-chase photoconversion, 5-ethynyl-2'-deoxyuridine proliferation, migration, and apoptosis assays were performed for functional analysis.Subsequently, derivatization of ethynyl-substituted triptycenes was studied to yieldthe respective propiolic acid and ethynylphosphine derivatives.Additionally, we report the transformation of 2,6,14- or 2,7,14-triaminotriptycenes to the corresponding ethynyl-substituted triptycenes via their tribromo derivatives.
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更新时间:2024/12/22 16:02:16