prepossessing
From Longman Dictionary of Contemporary Englishprepossessingpre‧pos‧sess‧ing /ˌpriːpəˈzesɪŋ◂/ adjective formal NICElooking attractive or pleasant a prepossessing smileExamples from the Corpusprepossessing• The Intelligence service was even prepared to give young Hans a second look, even though he was not a prepossessing sight.• It is not a prepossessing start, as the following example from my past experience as a social worker suggests.