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单词 lewis, gilbert newton
释义 DictionarySeeLewis acid

Lewis, Gilbert Newton


Lewis, Gilbert Newton,

1875–1946, American chemist, b. Weymouth, Mass., grad. Harvard (B.A., 1896; Ph.D., 1899). He taught at Harvard and at the Massachusetts Institute of Technology (1907–12) and from 1912 was professor of physical chemistry and dean of the college of chemistry, Univ. of California. His recognition of the importance of the electron pair bond led to a revision of the theory of valence. He also made special studies in thermodynamics, formulated the Lewis theory of acids and basesacids and bases,
two related classes of chemicals; the members of each class have a number of common properties when dissolved in a solvent, usually water. Properties
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, and with Harold C. Urey, a graduate student of his, discovered heavy water (1932). He wrote Valence and the Structure of Atoms and Molecules (1923).

Lewis, Gilbert Newton

 

Born Oct. 23, 1875, in Wey-mouth, Mass., near Boston; died Mar. 23, 1946, in Berkeley, Calif. American physical chemist; member of the US National Academy of Sciences in Washington, D.C.

Lewis graduated from Harvard University in 1896 and became a professor at the University of California at Berkeley in 1912. Most of his research dealt with chemical thermodynamics and a theory of the structure of matter. Lewis proposed a new formulation of the third principle of thermodynamics, contributing to a more precise definition of absolute entropy. He developed methods of calculating the free energy of chemical reactions and introduced the concepts of thermodynamic activity (1907) and volatility. He proposed the electron theory of chemical bonding (1912-16) and was the first to produce heavy water D2O (1933, jointly with R. MacDonald) and to isolate deuterium, the heavy isotope of hydrogen. A number of his studies were devoted to the theory of acids and bases, the formation of complexes, solubility, and the chromaticity of organic compounds. Lewis inspired a number of followers among his fellow chemists. He was made an honorary member of the Academy of Sciences of the USSR in 1942.

WORKS

In Russian translation:
Anatomiia nauki. Moscow-Leningrad, 1929.
Khimicheskaia termodinamika. Leningrad, 1936. (Jointly with M. Randall.)

REFERENCE

Kapustinskii, A. F. “G. N. L’iuis i ego trudy v oblasti khimii.” Izvestiia AN SSSR. Otdeleniie khimicheskikh nauk, 1942, no. 5.

Lewis, Gilbert Newton


Lewis, Gilbert Newton

U.S. physical chemist, 1875–1946. He discovered the covalent bond and was the first to produce pure heavy water (deuterium oxide).

Lewis acid

A substance that accepts an electron pair from a base, forming a covalent bond with the base.

Lewis base

A substance that donates an electron pair to an acid, forming a covalent bond with the acid.
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