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单词 nitroform
释义

Nitroform


Ni´tro`form


n.1.(Chem.) A nitro derivative of methane, analogous to chloroform, obtained as a colorless oily or crystalline substance, CH.(NO2)3, quite explosive, and having well-defined acid properties.

Nitroform


Nitroform

 

trinitromethane, HC(NO2)3, a readily congealing liquid with a characteristic odor. Melting point, 22°–23°C; boiling point, 45°-47°C (at 1.92 kilonewtons per sq m, or 22 mm of mercury); density, 1.479 g/cm3 (20°C).

Nitroform is readily soluble in water and organic solvents. It decomposes during storage and explodes upon impact, detonation, or rapid heating. It is a strong acid, with a dissociation constant of 6.8 × 10-1 at 20°C; it forms salts with metals and organic bases—for example, KC(NO2)3. It is produced by the action of concentrated nitric acid on acetylene (in the presence of mercury nitrate) or from tetranitromethane.

Nitroform is used in the preparation of nitro compounds under laboratory conditions.

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