Tantaloniobate

any of a group of minerals that are natural compounds in which Ta and Nb form the compound. Tantaloniobates have the generalized formula A_nB_mX_p, where A represents the large cations (Ca²⁺, TR³⁺ [rare-earth elements], U⁴⁺, Th⁴⁺, Na ⁺, or, less frequently, Pb²⁺, Sb³⁺, or Bi³⁺) or medium cations (Fe²⁺, Mn²⁺, or Mg²⁺), B represents Nb⁵⁺ and Ta⁵⁺, which may be replaced by Ti⁴⁺, Sn⁴⁺, or Fe^3-, and X stands for O^2-, OH^-, or F^-. With a close degree of covalence for the bond between the anions X and the cations of groups A and B, tantaloniobates approach the multiple oxides.

The class of tantaloniobates comprises more than 100 mineral species and their varieties. The main minerals are columbite, tantalite, loparite, and pyrochlore; ixiolite, (Nb,Ta,Sn,W,Sc)₃O₆; samarskite; euxinite, (Y,TR)(Nb,Ta,Ti)₂O₆; and microlite, Ca₂(Ta,Nb)₂O₆(F,OH). The structural basis of the tantaloniobates is niobium-oxygen or tantalum-oxygen octahedrons, (Nb,Ta)O₆, bonded together by cations of group A.

Tantaloniobates containing U, Th, and TR are metamict and strongly radioactive and contain a variable quantity of water. Polymorphous modifications are common. Tantaloniobates form fine inclusions in rocks. Large segregations are rare; crystals are typical of loparite, pyrochlore, and columbite-tantalum. The coloration of tantaloniobates is black, dark brown, or brownish yellow; simpsonite is light yellow, and manganotantalite is pink. The minerals are usually semitransparent or translucent, with a vitreous luster; the metamict varieties have a resinous luster. The hardness of tantaloniobates on Mohs’ scale ranges from 4.5 to 8 but is usually 5–6; that of the metamict varieties is lower. Densities are 3,500–9,000 kg/m³, depending on the Ta and Ti content. Tantaloniobates that contain Fe, Mn, and rare-earth elements are weakly magnetized.

Tantaloniobates are accessory minerals in granites and nepheline syenites; they form higher concentrations in granitic pegmatites, alkaline pegmatites, rare-metal albitized granites, feldspar metasomatites, carbonatites, lujauvrites, and foyaites. They are the ores for Ta, Ni, and rare-earth elements.

REFERENCE

Geokhimiia, mineralogiia i genetkheskie tipy mestorozhdenii redkikh elementov, vol. 2. Moscow, 1964. Section 11.

A. I. GINZBURG

单词	tantaloniobate
释义	Tantaloniobate Tantaloniobate any of a group of minerals that are natural compounds in which Ta and Nb form the compound. Tantaloniobates have the generalized formula A_nB_mX_p, where A represents the large cations (Ca²⁺, TR³⁺ [rare-earth elements], U⁴⁺, Th⁴⁺, Na ⁺, or, less frequently, Pb²⁺, Sb³⁺, or Bi³⁺) or medium cations (Fe²⁺, Mn²⁺, or Mg²⁺), B represents Nb⁵⁺ and Ta⁵⁺, which may be replaced by Ti⁴⁺, Sn⁴⁺, or Fe^3-, and X stands for O^2-, OH^-, or F^-. With a close degree of covalence for the bond between the anions X and the cations of groups A and B, tantaloniobates approach the multiple oxides. The class of tantaloniobates comprises more than 100 mineral species and their varieties. The main minerals are columbite, tantalite, loparite, and pyrochlore; ixiolite, (Nb,Ta,Sn,W,Sc)₃O₆; samarskite; euxinite, (Y,TR)(Nb,Ta,Ti)₂O₆; and microlite, Ca₂(Ta,Nb)₂O₆(F,OH). The structural basis of the tantaloniobates is niobium-oxygen or tantalum-oxygen octahedrons, (Nb,Ta)O₆, bonded together by cations of group A. Tantaloniobates containing U, Th, and TR are metamict and strongly radioactive and contain a variable quantity of water. Polymorphous modifications are common. Tantaloniobates form fine inclusions in rocks. Large segregations are rare; crystals are typical of loparite, pyrochlore, and columbite-tantalum. The coloration of tantaloniobates is black, dark brown, or brownish yellow; simpsonite is light yellow, and manganotantalite is pink. The minerals are usually semitransparent or translucent, with a vitreous luster; the metamict varieties have a resinous luster. The hardness of tantaloniobates on Mohs’ scale ranges from 4.5 to 8 but is usually 5–6; that of the metamict varieties is lower. Densities are 3,500–9,000 kg/m³, depending on the Ta and Ti content. Tantaloniobates that contain Fe, Mn, and rare-earth elements are weakly magnetized. Tantaloniobates are accessory minerals in granites and nepheline syenites; they form higher concentrations in granitic pegmatites, alkaline pegmatites, rare-metal albitized granites, feldspar metasomatites, carbonatites, lujauvrites, and foyaites. They are the ores for Ta, Ni, and rare-earth elements. REFERENCE Geokhimiia, mineralogiia i genetkheskie tipy mestorozhdenii redkikh elementov, vol. 2. Moscow, 1964. Section 11. A. I. GINZBURG
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