Sol-gel process

A chemical synthesis technique for preparing gels, glasses, and ceramic powders. The sol-gel process generally involves the use of metal alkoxides, which undergo hydrolysis and condensation polymerization reactions to give gels.

The production of glasses by the sol-gel method permits preparation of glasses at far lower temperatures than is possible by using conventional melting. It also makes possible synthesis of compositions that are difficult to obtain by conventional means because of problems associated with volatilization, high melting temperatures, or crystallization. In addition, the sol-gel approach is a high-purity process that leads to excellent homogeneity. Finally, the sol-gel approach is adaptable to producing films and fibers as well as bulk pieces. See Glass

The sol-gel process comprises solution, gelation, drying, and densification. The preparation of a silica glass begins with an appropriate alkoxide which is mixed with water and a mutual solvent to form a solution. Hydrolysis leads to the formation of silanol groups (Si—OH). These species are only intermediates. Subsequent condensation reactions produce siloxane bonds (Si—O—Si). The silica gel formed by this process leads to a rigid, interconnected three-dimensional network consisting of submicrometer pores and polymeric chains. During the drying process (at ambient pressure), the solvent liquid is removed and substantial shrinkage occurs. The resulting material is known as a xerogel. When solvent removal occurs under hypercritical (supercritical) conditions, the network does not shrink and a highly porous, low-density material known as an aerogel is produced. Heat treatment of a xerogel at elevated temperature produces viscous sintering (shrinkage of the xerogel due to a small amount of viscous flow) and effectively transforms the porous gel into a dense glass.

Materials used in the sol-gel process include inorganic compositions that possess specific properties such as ferroelectricity, electrochromism, or superconductivity. The most successful applications utilize the composition control, microstructure control, purity, and uniformity of the method combined with the ability to form various shapes at low temperatures. Films and coatings were the first commercial applications of the sol-gel process. The development of sol-gel-based optical materials has also been quite successful, and applications include monoliths (lenses, prisms, lasers), fibers (waveguides), and a wide variety of optical films. Other important applications of sol-gel technology utilize controlled porosity and high surface area for catalyst supports, porous membranes, and thermal insulation. See Materials science and engineering

单词	sol-gel process
释义	Sol-gel process Sol-gel process A chemical synthesis technique for preparing gels, glasses, and ceramic powders. The sol-gel process generally involves the use of metal alkoxides, which undergo hydrolysis and condensation polymerization reactions to give gels. The production of glasses by the sol-gel method permits preparation of glasses at far lower temperatures than is possible by using conventional melting. It also makes possible synthesis of compositions that are difficult to obtain by conventional means because of problems associated with volatilization, high melting temperatures, or crystallization. In addition, the sol-gel approach is a high-purity process that leads to excellent homogeneity. Finally, the sol-gel approach is adaptable to producing films and fibers as well as bulk pieces. See Glass The sol-gel process comprises solution, gelation, drying, and densification. The preparation of a silica glass begins with an appropriate alkoxide which is mixed with water and a mutual solvent to form a solution. Hydrolysis leads to the formation of silanol groups (Si—OH). These species are only intermediates. Subsequent condensation reactions produce siloxane bonds (Si—O—Si). The silica gel formed by this process leads to a rigid, interconnected three-dimensional network consisting of submicrometer pores and polymeric chains. During the drying process (at ambient pressure), the solvent liquid is removed and substantial shrinkage occurs. The resulting material is known as a xerogel. When solvent removal occurs under hypercritical (supercritical) conditions, the network does not shrink and a highly porous, low-density material known as an aerogel is produced. Heat treatment of a xerogel at elevated temperature produces viscous sintering (shrinkage of the xerogel due to a small amount of viscous flow) and effectively transforms the porous gel into a dense glass. Materials used in the sol-gel process include inorganic compositions that possess specific properties such as ferroelectricity, electrochromism, or superconductivity. The most successful applications utilize the composition control, microstructure control, purity, and uniformity of the method combined with the ability to form various shapes at low temperatures. Films and coatings were the first commercial applications of the sol-gel process. The development of sol-gel-based optical materials has also been quite successful, and applications include monoliths (lenses, prisms, lasers), fibers (waveguides), and a wide variety of optical films. Other important applications of sol-gel technology utilize controlled porosity and high surface area for catalyst supports, porous membranes, and thermal insulation. See Materials science and engineering
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