释义 |
macrocyclic /ˌmakrə(ʊ)ˈsʌɪklɪk / /ˌmakrə(ʊ)ˈsɪklɪk/adjective ChemistryRelating to or denoting a ring composed of a relatively large number of atoms, such as occur in haem, chlorophyll, and several natural antibiotics.The polar head is a macrocyclic lactone ring containing nine amino acid residues, three of which have positive charges, whereas one has negative charge....- The intermolecular interactions between the viologens and the macrocyclic molecule were investigated in a solution before photoirradiation.
- Collectively, they are called tetraamido macrocyclic ligands or TAML for short.
Derivativesmacrocycle noun ...- Their device was based on a supramolecular system consisting of a p-electron-donating macrocycle threaded with a p-electron-accepting wire-like molecule.
- Very few porphyrins are known to form J-aggregates, the main requisite being the zwitterionic character with the protonation of the pyrrole nitrogen in the macrocycle.
- However, similar spectral changes can also be produced by the protonation of the macrocycle at the azomethine nitrogens, although there are very few reports in which this phenomenon is discussed.
|