| 释义 |
osmate Chem.|ˈɒzmeɪt|
[f. osmium + -ate1.]
A salt or ester of osmic acid (H2OsO4) in which osmium has an oxidation state of 6, and in the case of alkali metals having the formula M2[OsO2(OH)4] and obtainable by the action of a reducing agent such as alcohol on an alkaline solution of osmium tetroxide.
1852G. Fownes Man. Elem. Chem. (ed. 4) ii. 368 Osmate of potassa is produced when the metal is fused with nitre. 1868J. P. Cooke First Princ. Chem. Philos. (1870) xix. 420 Osmic anhydride..is unknown, but potassic osmate..can easily be obtained. 1909L. Kahlenberg Outl. Chem. xxxi. 525 The chlorides OsCl2, Os2Cl6, and OsCl4 are known, as are also osmates like K2OsO4.2H2O. 1950N. V. Sidgwick Chem. Elements II. 1501 The tetroxide reacts with potassium or caesium hydroxide in methyl alcohol to give the tetramethyl osmate (MO)2Osvi(O·CH3)4. 1973S. E. Livingstone in J. C. Bailar et al. Comprehensive Inorg. Chem. III. xliii. 1230 Potassium osmate, originally formulated as K2OsO4·2H2O, has the octahedral structure K2[OsO2(OH)4]. |