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单词 cinnoline
释义

cinnolinen.

/ˈsɪnəʊlɪn/
Etymology: < German cinnolin (V. von Richter 1883, in Berichte der Deutsch. Chem. Ges. 16 677); compare quinoline n.
Chemistry.
A poisonous crystalline base, C8H6N2.
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the world > matter > chemistry > organic chemistry > poisons > [noun] > others
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muscarine1869
cinnoline1883
saprine1887
isocyanic acid1891
mescaline1896
toxicodendrol1898
tube curare1898
tulipine1900
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Lewisite1921
organochloride1966
1883 Jrnl. Chem. Soc. 44 1105 Cinnoline-derivatives. By V. v. Richter.
1883 Jrnl. Chem. Soc. 44 1105 This base may be looked upon as quinoline in which one CH-group has been replaced by N, and the author therefore proposes the name cinnoline for it.
1929 Encycl. Brit. V. 386/2 The fusion of pyridazine with benzene may result in either cinnoline or phthalazine.
1946 Jrnl. Amer. Chem. Soc. 68 1310 (title) 4-Substituted Cinnoline Derivatives.
1946 Jrnl. Amer. Chem. Soc. 68 1310 Work on the synthesis of cinnoline derivatives is limited, but has shown that the most practical method of obtaining such compounds..involves the spontaneous cyclization of diazotized o-aminophenyl~ethylenes.
1946 Jrnl. Amer. Chem. Soc. 68 1310 Cinnoline-4-carboxylic acid was esterified readily.
1965 Austral. Jrnl. Chem. 18 713 The non-uniform effect of the heteroatom on ortho coupling constants in the aromatic ring noted previously is again observed in quinazoline and cinnoline.
This entry has not yet been fully updated (first published 1933; most recently modified version published online June 2018).
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n.1883
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