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单词 alloxantin
释义

alloxantinn.

Brit. /aləkˈsantɪn/, U.S. /ˌæləkˈsæntən/
Forms: 1800s– alloxantin, 1800s– alloxantine.
Origin: A borrowing from German. Etymon: German Alloxantin.
Etymology: < German Alloxantin (F. Wöhler & J. Liebig 1838, in Ann. der Chemie u. Pharmacie 26 262), perhaps < all- + ant- + -in (all in Allantoin allantoin n.) with insertion of ox- (in Oxalsäure oxalic acid: see oxalic adj.).In form alloxantine probably after French alloxantine (1838; < German).
Chemistry.
A crystalline heterocyclic compound formed by the reaction of alloxan and its reduction product dialuric acid.Alloxantin is a bipyrimidine derivative; C8H6N4O6.
ΚΠ
1839 London & Edinb. Philos. Mag. 14 232 It frequently happens that on dissolving the impure alloxan, for the purpose of purifying by a second crystallization, a portion of alloxantin is obtained.
1853 J. L. W. Thudichum Treat. Pathol. Urine 81 On dissolving uric acid in dilute nitric acid, alloxantine is obtained.
1874 Chem. News 16 Oct. 179/2 Though alloxantin is thus readily got from murexide, the latter is not a compound of the former with NH3.
1924 J. B. Cohen Pract. Org. Chem. (ed. 3) 334 The filtrate is saturated with hydrogen sulphide, and yields..crystalline crusts, often of a reddish tint, of alloxantin mixed with sulphur.
1968 Radiation Res. 33 136 Alloxantin dissociates in water to form alloxan and dialuric acid.
2007 G. Singh Chem. Amino-acids & Proteins iv. 211 When heated with ammonia in alcoholic solution, alloxantin forms murexide, which is the ammonium salt of purpuric acid (an unstable compound).
This entry has been updated (OED Third Edition, September 2012; most recently modified version published online December 2021).
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n.1839
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