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单词 manganocene
释义

manganocenen.

Brit. /maŋˈɡanə(ʊ)siːn/, /manˈɡanə(ʊ)siːn/, U.S. /ˌmæŋˈɡænəˌsin/, /ˌmænˈɡænəˌsin/
Origin: Formed within English, by compounding. Etymons: mangano- comb. form2, ferrocene n.
Etymology: < mangano- comb. form2 + -cene (in ferrocene n.).
Chemistry.
An organometallic compound, Mn(C5H5)2, which at room temperature adopts a polymeric structure, consisting of manganese atoms bonded to hydrocarbon rings in a zigzag chain.
ΘΚΠ
the world > matter > chemistry > organic chemistry > organometallurgy > [noun] > organometallic compounds
cacodyl1850
carbide1898
cemented carbide1932
ferrocene1952
manganocene1968
1968 G. E. Coates et al. Princ. Organometallic Chem. vii. 199 Chemical evidence and..magnetic susceptibility data suggest that manganocene is largely ionic.
1984 N. N. Greenwood & A. Earnshaw Chem. of Elements (1986) xxiv. 1238 When MnCl2 in thf [sc. tetrahydrofuran] is treated with C5H5Na, amber-coloured crystals of manganocene..mp 172°, are produced.
1989 C. Elschenbroich & A. Salzer Organometallics xv. 325 Manganocene Cp2Mn in the solid state has a chain structure without individual sandwich entities.
This is a new entry (OED Third Edition, September 2000; most recently modified version published online March 2022).
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n.1968
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