单词 | olation |
释义 | olationn. Chemistry and Tanning. Conversion of a complex into an ol form; the linking of metal atoms by hydroxyl ligands.Frequently with reference to chromium compounds used in tanning. ΘΚΠ the world > matter > chemistry > chemical reactions or processes > [noun] > chemical reactions or processes (named) > miscellaneous other processes redintegrationa1550 decoction1555 fixion1555 cementation1592 fumigation1617 spiritualization1651 retortion1657 rocking1673 phosphorizationa1687 concentration1689 humectation1706 animalization1733 hyperoxygenation1793 bituminization1804 assimilation1830 metamorphosis1843 transformation1857 retorting1858 tincturation1860 regeneration1869 nitrification1880 diagenesis1886 aluminothermy1900 aluminothermics1902 photoprocess1910 olation1931 mass transfer1937 reconcentration1956 tritiation1961 borohydride reduction1965 1931 Jrnl. Physical Chem. 35 27 Bjerrum..postulated that perhaps the hydroxo groups in the complex ions were becoming more firmly bound to form larger complexes... Bjerrum called this process ‘olation’. 1948 J. H. Bowes in Progress Leather Sci. 1920–1945 xxvi. 524 Stiasny..termed this process ‘olation’ and postulated that hydroxy groups react immediately with acid whereas ‘ol-groups’ only react after deolation. 1969 T. C. Thorstensen Pract. Leather Technol. viii. 120 At higher temperatures there is greater fixation of the chrome tanning compound by the hide protein and greater olation of the chrome complexes. 1974 D. Nicholls Inorg. Complexes iii. 26 The hydroxo-aquo complexes may combine together in a process known as olation. 2000 Appl. Organometallic Chem. 14 660 Structures that may lead to polynuclear chromium complexes to cross-link the collagen fibrils in chromium tanning processes are modeled. Pathways are suggested to the olation reaction. This entry has been updated (OED Third Edition, March 2004; most recently modified version published online March 2022). < n.1931 |
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