| 释义 |
borohydride Chem.|ˌbɔərəʊˈhaɪdraɪd|
[f. boro- + hydride.]
A compound containing the radical -BH4, or a substituted form of this radical. Hence borohydride reduction, selective reduction of a compound by a borohydride.
1940Jrnl. Amer. Chem. Soc. LXII. 3422 Its probable structure has led us to adopt the name aluminium borohydride. Ibid. 3430 The basic structures of the aluminium, beryllium and lithium borohydrides are closely related. 1961W. Gerrard Org. Chem. Boron x. 136 Selectivity of reduction can be achieved by employing sodium borohydride in conjunction with a particular solvent. 1965H. O. House Mod. Synthetic Reactions ii. 40 Sodium borohydride reductions of α, β-unsaturated compounds are only rarely complicated by reduction of the carbon-carbon double bond. |